TY - JOUR

T1 - Precipitation-based grain boundary design alters Inter- to Trans-granular Fracture in AlCrN Thin Films

AU - Meindlhumer, Michael

AU - Ziegelwanger, Tobias

AU - Zalesak, Jakub

AU - Hans, Marcus

AU - Löfler, Lukas

AU - Spor, Stefan

AU - Jäger, Nikolaus

AU - Stark, Andreas

AU - Hruby, Hynek

AU - Daniel, Rostislav

AU - Holec, David

AU - Schneider, Jochen M.

AU - Mitterer, Christian

AU - Keckes, Jozef

N1 - https://doi.org/10.1016/j.actamat.2022.118156

PY - 2022/9/15

Y1 - 2022/9/15

N2 - Despite their high hardness and indentation modulus, nanostructured crystalline ceramic thin films produced by physical vapour deposition usually lack sufficient fracture strength and toughness. This brittleness is often caused by underdense columnar grain boundaries of low cohesive energy, which serve as preferential paths for crack propagation. In this study, mechanical and structural properties of arc-evaporated Al0.9Cr0.1N thin films were analyzed using micromechanical tests, electron microscopy, atom probe tomography and in situ high-energy high-temperature grazing incidence transmission X-ray diffraction. Vacuum annealing at 1100°C resulted in the formation of regularly-distributed globular cubic Cr(Al)N and elongated cubic CrN precipitates at intracrystalline Cr-enriched sublayers and at columnar grain boundaries with sizes of ∼5 and ∼30 nm, respectively. Consequently, in situ micromechanical testing before and after the heat treatment revealed simultaneous enhancement of Young's modulus, fracture stress and fracture toughness by ∼35, 60 and 10%, respectively. The annealing-induced concomitant improvement of toughness and strength was inferred to precipitations observed within grains as well as at grain boundaries enhancing the cohesive energy of the grain boundaries and thereby altering the crack propagation pathway from inter- to transcrystalline. The here reported experimental data unveil the hitherto untapped potential of precipitation-based grain boundary design for the improvement of mechanical properties of transition metal nitride thin films.

AB - Despite their high hardness and indentation modulus, nanostructured crystalline ceramic thin films produced by physical vapour deposition usually lack sufficient fracture strength and toughness. This brittleness is often caused by underdense columnar grain boundaries of low cohesive energy, which serve as preferential paths for crack propagation. In this study, mechanical and structural properties of arc-evaporated Al0.9Cr0.1N thin films were analyzed using micromechanical tests, electron microscopy, atom probe tomography and in situ high-energy high-temperature grazing incidence transmission X-ray diffraction. Vacuum annealing at 1100°C resulted in the formation of regularly-distributed globular cubic Cr(Al)N and elongated cubic CrN precipitates at intracrystalline Cr-enriched sublayers and at columnar grain boundaries with sizes of ∼5 and ∼30 nm, respectively. Consequently, in situ micromechanical testing before and after the heat treatment revealed simultaneous enhancement of Young's modulus, fracture stress and fracture toughness by ∼35, 60 and 10%, respectively. The annealing-induced concomitant improvement of toughness and strength was inferred to precipitations observed within grains as well as at grain boundaries enhancing the cohesive energy of the grain boundaries and thereby altering the crack propagation pathway from inter- to transcrystalline. The here reported experimental data unveil the hitherto untapped potential of precipitation-based grain boundary design for the improvement of mechanical properties of transition metal nitride thin films.

KW - AlCrN

KW - Heat treatment

KW - Grain-boundary segregation engineering

KW - Micromechanics

U2 - 10.1016/j.actamat.2022.118156

DO - 10.1016/j.actamat.2022.118156

M3 - Article

VL - 237.2022

JO - Acta materialia

JF - Acta materialia

SN - 1359-6454

IS - 15 September

M1 - 118156

ER -