Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system

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Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system. / Gruber, Georg; Lassnig, Alice ; Žák, Stanislav et al.
In: Surface & coatings technology, Vol. 439.2022, No. 15 June, 128446, 22.04.2022.

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Gruber G, Lassnig A, Žák S, Gammer C, Cordill MJ, Franz R. Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system. Surface & coatings technology. 2022 Apr 22;439.2022(15 June):128446. Epub 2022 Apr 22. doi: 10.1016/j.surfcoat.2022.128446

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@article{e9b26fc768c3416baffbd2f8fbe1fb88,
title = "Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system",
abstract = "To explore structure and properties of refractory high entropy alloy (HEA) thin films, targets with five different equimolar compositions based on the MoNbTaW system and alloyed with Ti, V, Cr, Mn or Hf were used for the synthesis of films by high power impulse magnetron sputtering. All HEA films showed a body-centered cubic structure and a dense, columnar morphology as revealed by X-ray diffraction and transmission electron microscopy, respectively. Alloying of the additional element affects the film stress and the mechanical properties. The overall compressive stress state present in the films was distributed inhomogeneously with an expected gradient along the film growth direction. Hardness and Young's modulus values ranging from 14 to 17 GPa and 230 to 295 GPa, respectively, were measured by nanoindentation.",
author = "Georg Gruber and Alice Lassnig and Stanislav {\v Z}{\'a}k and Christoph Gammer and Cordill, {Megan J.} and Robert Franz",
year = "2022",
month = apr,
day = "22",
doi = "10.1016/j.surfcoat.2022.128446",
language = "English",
volume = "439.2022",
journal = "Surface & coatings technology",
issn = "0257-8972",
publisher = "Elsevier",
number = "15 June",

}

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TY - JOUR

T1 - Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system

AU - Gruber, Georg

AU - Lassnig, Alice

AU - Žák, Stanislav

AU - Gammer, Christoph

AU - Cordill, Megan J.

AU - Franz, Robert

PY - 2022/4/22

Y1 - 2022/4/22

N2 - To explore structure and properties of refractory high entropy alloy (HEA) thin films, targets with five different equimolar compositions based on the MoNbTaW system and alloyed with Ti, V, Cr, Mn or Hf were used for the synthesis of films by high power impulse magnetron sputtering. All HEA films showed a body-centered cubic structure and a dense, columnar morphology as revealed by X-ray diffraction and transmission electron microscopy, respectively. Alloying of the additional element affects the film stress and the mechanical properties. The overall compressive stress state present in the films was distributed inhomogeneously with an expected gradient along the film growth direction. Hardness and Young's modulus values ranging from 14 to 17 GPa and 230 to 295 GPa, respectively, were measured by nanoindentation.

AB - To explore structure and properties of refractory high entropy alloy (HEA) thin films, targets with five different equimolar compositions based on the MoNbTaW system and alloyed with Ti, V, Cr, Mn or Hf were used for the synthesis of films by high power impulse magnetron sputtering. All HEA films showed a body-centered cubic structure and a dense, columnar morphology as revealed by X-ray diffraction and transmission electron microscopy, respectively. Alloying of the additional element affects the film stress and the mechanical properties. The overall compressive stress state present in the films was distributed inhomogeneously with an expected gradient along the film growth direction. Hardness and Young's modulus values ranging from 14 to 17 GPa and 230 to 295 GPa, respectively, were measured by nanoindentation.

U2 - 10.1016/j.surfcoat.2022.128446

DO - 10.1016/j.surfcoat.2022.128446

M3 - Article

VL - 439.2022

JO - Surface & coatings technology

JF - Surface & coatings technology

SN - 0257-8972

IS - 15 June

M1 - 128446

ER -