Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system
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In: Surface & coatings technology, Vol. 439.2022, No. 15 June, 128446, 22.04.2022.
Research output: Contribution to journal › Article › Research › peer-review
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TY - JOUR
T1 - Synthesis and structure of refractory high entropy alloy thin films based on the MoNbTaW system
AU - Gruber, Georg
AU - Lassnig, Alice
AU - Žák, Stanislav
AU - Gammer, Christoph
AU - Cordill, Megan J.
AU - Franz, Robert
PY - 2022/4/22
Y1 - 2022/4/22
N2 - To explore structure and properties of refractory high entropy alloy (HEA) thin films, targets with five different equimolar compositions based on the MoNbTaW system and alloyed with Ti, V, Cr, Mn or Hf were used for the synthesis of films by high power impulse magnetron sputtering. All HEA films showed a body-centered cubic structure and a dense, columnar morphology as revealed by X-ray diffraction and transmission electron microscopy, respectively. Alloying of the additional element affects the film stress and the mechanical properties. The overall compressive stress state present in the films was distributed inhomogeneously with an expected gradient along the film growth direction. Hardness and Young's modulus values ranging from 14 to 17 GPa and 230 to 295 GPa, respectively, were measured by nanoindentation.
AB - To explore structure and properties of refractory high entropy alloy (HEA) thin films, targets with five different equimolar compositions based on the MoNbTaW system and alloyed with Ti, V, Cr, Mn or Hf were used for the synthesis of films by high power impulse magnetron sputtering. All HEA films showed a body-centered cubic structure and a dense, columnar morphology as revealed by X-ray diffraction and transmission electron microscopy, respectively. Alloying of the additional element affects the film stress and the mechanical properties. The overall compressive stress state present in the films was distributed inhomogeneously with an expected gradient along the film growth direction. Hardness and Young's modulus values ranging from 14 to 17 GPa and 230 to 295 GPa, respectively, were measured by nanoindentation.
U2 - 10.1016/j.surfcoat.2022.128446
DO - 10.1016/j.surfcoat.2022.128446
M3 - Article
VL - 439.2022
JO - Surface & coatings technology
JF - Surface & coatings technology
SN - 0257-8972
IS - 15 June
M1 - 128446
ER -