Impact of annealing and hydrogenation on the superconducting transition temperature of (TiNbMoTaW)Nx high entropy alloy nitride films

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Authors

  • Gabriel Pristáš
  • Július Bačkai
  • Filip Košuth
  • Radoven Bures
  • Mária Fáberová
  • Slavomír Gabáni
  • Oleksandr Onufriienko
  • Serhii Vorobiov
  • Karol Flachbart

External Organisational units

  • Faculty of Science
  • Institute of Experimental Physics Slovak Academy of Sciences

Abstract

Very recently it was shown that incorporation of nitrogen into Ti 0.2Nb 0.2Mo 0.2Ta 0.2W 0.2 high-entropy alloy films leads to a considerable superconducting transition temperature T C enhancement in corresponding (TiNbMoTaW) 1.0N x nitrides. Here we report, independently, about the impact of subsequent annealing and the influence of additional hydrogen incorporation on these films, which should lead to a further enhancement of T C. However, the expected T C increase was not observed, on the contrary, both annealing of films at 800 °C in vacuum and incorporation of hydrogen into these films led to a reduction of T C. Analysis of the results shows that in case of annealing this is related to nitrogen release from the films, in case of hydrogenation to reductions of the density of states at the Fermi level and of the electron-phonon interaction.

Details

Original languageEnglish
Article number107851
Pages (from-to)1-7
Number of pages7
JournalSolid State Sciences : SSS
Volume161.2025
Issue numberMarch
DOIs
Publication statusPublished - 1 Feb 2025