TY - THES

T1 - Simulation and Economic Analysis of 5-Hydroxymethylfurfural Conversion to 2,5-Furandicarboxylic Acid

AU - Triebl, Christoph

N1 - embargoed until null

PY - 2012

Y1 - 2012

N2 - Due to rising oil price and environmental aspects, research on alternatives for petroleum based chemicals and fuels is growing in recent years. Biomass is one potential raw material for producing non-petroleum derived chemicals and fuels. Different catalysts and reaction steps are required to generate the same products in comparison with the petroleum based processes. One possible starting material for biobased chemicals is 5-hydroxymethylfurfural (HMF), which is derived from monosaccharides, such as glucose and fructose. HMF could be converted into different chemicals and fuels, such as 2,5-furandicarboxylic acid (FDCA), which is generated by catalytic oxidation of HMF. According to a report of the Department of Energy (DOE) in 2004, HMF and FDCA are one of the 12 biobased building blocks of the future. Simulations on the processes for producing and purifying FDCA from HMF were performed. A tubular reactor was used to generate FDCA from HMF in aqueous solvent using air as oxidant. For purification, two different processes were designed. In the first process, FDCA is solidified at a crystallizer and fed to a filter or a hydrocyclone. The purity of FDCA in the product stream in the processes using the hydrocyclone and the filter are 3 wt% and 98 wt%, respectively. The second process produces liquid FDCA at a purity of 97 wt%. Due to the high boiling point of FDCA, separation from the aqueous acetic acid solvent is impossible. For this purpose FDCA is extracted by the solvent trioctylamine and removed using distillation. Acetic acid and trioctylamine are separated in a second distillation column, at which a partial condenser is used to minimize cooling cost. At all processes, economy analysis was carried out to estimate minimum sale price of FDCA. In the processes with the hydrocyclone and the filter, FDCA price is estimated to be 4435 $/t and 3157 $/t, respectively. Estimated minimum sale price of FDCA in the process with the distillation columns is 3885 $/t. Sensitivity analysis shows that selectivity of FDCA and conversion of HMF have small impact on FDCA price due to recycling of HMF and the intermediates, whereas plant capacity, catalyst cost and HMF cost have more profound effect on the price of FDCA.

AB - Due to rising oil price and environmental aspects, research on alternatives for petroleum based chemicals and fuels is growing in recent years. Biomass is one potential raw material for producing non-petroleum derived chemicals and fuels. Different catalysts and reaction steps are required to generate the same products in comparison with the petroleum based processes. One possible starting material for biobased chemicals is 5-hydroxymethylfurfural (HMF), which is derived from monosaccharides, such as glucose and fructose. HMF could be converted into different chemicals and fuels, such as 2,5-furandicarboxylic acid (FDCA), which is generated by catalytic oxidation of HMF. According to a report of the Department of Energy (DOE) in 2004, HMF and FDCA are one of the 12 biobased building blocks of the future. Simulations on the processes for producing and purifying FDCA from HMF were performed. A tubular reactor was used to generate FDCA from HMF in aqueous solvent using air as oxidant. For purification, two different processes were designed. In the first process, FDCA is solidified at a crystallizer and fed to a filter or a hydrocyclone. The purity of FDCA in the product stream in the processes using the hydrocyclone and the filter are 3 wt% and 98 wt%, respectively. The second process produces liquid FDCA at a purity of 97 wt%. Due to the high boiling point of FDCA, separation from the aqueous acetic acid solvent is impossible. For this purpose FDCA is extracted by the solvent trioctylamine and removed using distillation. Acetic acid and trioctylamine are separated in a second distillation column, at which a partial condenser is used to minimize cooling cost. At all processes, economy analysis was carried out to estimate minimum sale price of FDCA. In the processes with the hydrocyclone and the filter, FDCA price is estimated to be 4435 $/t and 3157 $/t, respectively. Estimated minimum sale price of FDCA in the process with the distillation columns is 3885 $/t. Sensitivity analysis shows that selectivity of FDCA and conversion of HMF have small impact on FDCA price due to recycling of HMF and the intermediates, whereas plant capacity, catalyst cost and HMF cost have more profound effect on the price of FDCA.

KW - FDCA

KW - HMF

KW - Bioraffinerie

KW - Biomasse

KW - Wirtschaftlichkeitsanalyse

KW - Prozesssimulation

KW - FDCA

KW - HMF

KW - biorefinery

KW - biomass

KW - economy analysis

KW - process simulation

M3 - Master's Thesis

ER -