TY - JOUR

T1 - Influence of Silicon and Tramp Elements on the High-temperature Oxidation of Steel in Direct Casting and Rolling Processes

AU - Gaiser, Georg

AU - Presoly, Peter

AU - Bernhard, Christian

AU - Baumgartner, Kerstin

AU - Grosseiber, Simon

N1 - Publisher Copyright: © 2024 The Iron and Steel Institute of Japan.

PY - 2024/7/15

Y1 - 2024/7/15

N2 - Oxidation processes are unavoidable in continuous casting and further hot processing of steel. A deeper understanding of the occurring phenomena such as intergranular oxidation and liquid metal infiltration of grain boundaries is essential to continuously improve the quality of the products. In this study, oxidation experiments were performed with simultaneous thermal analysis for two thin slab casting and rolling applications under near-process conditions up to the point prior to the first reduction stage. The experiments were performed for two low-carbon steels contaminated with undesirable tramp elements (Cu, Sn, …). In addition, the two steels contain Silicon at different levels. The results show that for the “Endless Strip Production” process (ESP), intergranular oxidation is significantly less pronounced compared to a “Thin Slab Casting and Rolling process” with a gas-fired tunnel furnace (TSCR TF). Due to the short process time at high temperatures in the ESP process, hardly any liquid metal infiltration by copper appears. In low silicon steel, intergranular oxidation results from various oxides, and liquid metal infiltration appears simultaneously in the TSCR TF process. Furthermore, the yield loss from oxidation is significantly higher in the TSCR TF process. The change from a natural gas combustion atmosphere to a hydrogen combustion atmosphere further increases the oxidation rate and results in a higher mass loss.

AB - Oxidation processes are unavoidable in continuous casting and further hot processing of steel. A deeper understanding of the occurring phenomena such as intergranular oxidation and liquid metal infiltration of grain boundaries is essential to continuously improve the quality of the products. In this study, oxidation experiments were performed with simultaneous thermal analysis for two thin slab casting and rolling applications under near-process conditions up to the point prior to the first reduction stage. The experiments were performed for two low-carbon steels contaminated with undesirable tramp elements (Cu, Sn, …). In addition, the two steels contain Silicon at different levels. The results show that for the “Endless Strip Production” process (ESP), intergranular oxidation is significantly less pronounced compared to a “Thin Slab Casting and Rolling process” with a gas-fired tunnel furnace (TSCR TF). Due to the short process time at high temperatures in the ESP process, hardly any liquid metal infiltration by copper appears. In low silicon steel, intergranular oxidation results from various oxides, and liquid metal infiltration appears simultaneously in the TSCR TF process. Furthermore, the yield loss from oxidation is significantly higher in the TSCR TF process. The change from a natural gas combustion atmosphere to a hydrogen combustion atmosphere further increases the oxidation rate and results in a higher mass loss.

KW - fayalite

KW - intergranular oxidation

KW - liquid metal infiltration

KW - low carbon steel

KW - rolling process

KW - thin slab casting

KW - tramp elements

UR - http://www.scopus.com/inward/record.url?scp=85198835232&partnerID=8YFLogxK

U2 - 10.2355/isijinternational.ISIJINT-2024-072

DO - 10.2355/isijinternational.ISIJINT-2024-072

M3 - Article

VL - 64.2024

SP - 1439

EP - 1449

JO - ISIJ international

JF - ISIJ international

SN - 0915-1559

IS - 9

ER -