In situ study and assessment of the phosphorus-induced solute drag effect on the grain boundary mobility of austenite

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In situ study and assessment of the phosphorus-induced solute drag effect on the grain boundary mobility of austenite. / Kern, Maximilian; Bernhard, Michael Christian; Kang, Youn-Bae et al.
In: Acta Materialia, Vol. 269.2024, No. 1 May, 119826, 09.03.2024.

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@article{3d5a78d838de4ae1aa56fec780647f47,
title = "In situ study and assessment of the phosphorus-induced solute drag effect on the grain boundary mobility of austenite",
abstract = "The solute drag effect of phosphorus (P) in the single-phase austenite (γ-Fe) region was studied under isothermal annealing conditions at temperatures of 1050 °C, 1150 °C, 1250 °C and 1350 °C. High-temperature laser scanning confocal microscopy (HT-LSCM) was used to observe and quantify in situ grain growth on the surface of three different samples containing 0.026 wt.-% P, 0.044 wt.-% P and 0.102 wt.-% P. The dependence of the arithmetic mean grain sizes on time and temperature were modeled mathematically using a simple ordinary differential equation (ODE) according to normal grain growth (NGG) theory. As no other major effects, i.e., Zener-pinning by precipitates, occurred under the selected experimental conditions, grain growth interference was only considered by grain boundary (GB) segregation of P. Thus, the total grain boundary mobility (M) was directly determined depending on the P content and isothermal annealing temperature. The fitted GB mobility values enabled the determination of an average binding energy value between impurity P atoms and grain boundaries (E0 = -1.1 - -0.6 eV) in the system. Finally, the GB segregation of P in γ-Fe was derived from the observed grain growth kinetics. The results showed reasonable agreement with calculations using segregation enthalpies from the literature.",
author = "Maximilian Kern and Bernhard, {Michael Christian} and Youn-Bae Kang and Christian Bernhard",
year = "2024",
month = mar,
day = "9",
doi = "10.1016/j.actamat.2024.119826",
language = "English",
volume = "269.2024",
journal = "Acta Materialia",
issn = "1359-6454",
publisher = "Elsevier",
number = "1 May",

}

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TY - JOUR

T1 - In situ study and assessment of the phosphorus-induced solute drag effect on the grain boundary mobility of austenite

AU - Kern, Maximilian

AU - Bernhard, Michael Christian

AU - Kang, Youn-Bae

AU - Bernhard, Christian

PY - 2024/3/9

Y1 - 2024/3/9

N2 - The solute drag effect of phosphorus (P) in the single-phase austenite (γ-Fe) region was studied under isothermal annealing conditions at temperatures of 1050 °C, 1150 °C, 1250 °C and 1350 °C. High-temperature laser scanning confocal microscopy (HT-LSCM) was used to observe and quantify in situ grain growth on the surface of three different samples containing 0.026 wt.-% P, 0.044 wt.-% P and 0.102 wt.-% P. The dependence of the arithmetic mean grain sizes on time and temperature were modeled mathematically using a simple ordinary differential equation (ODE) according to normal grain growth (NGG) theory. As no other major effects, i.e., Zener-pinning by precipitates, occurred under the selected experimental conditions, grain growth interference was only considered by grain boundary (GB) segregation of P. Thus, the total grain boundary mobility (M) was directly determined depending on the P content and isothermal annealing temperature. The fitted GB mobility values enabled the determination of an average binding energy value between impurity P atoms and grain boundaries (E0 = -1.1 - -0.6 eV) in the system. Finally, the GB segregation of P in γ-Fe was derived from the observed grain growth kinetics. The results showed reasonable agreement with calculations using segregation enthalpies from the literature.

AB - The solute drag effect of phosphorus (P) in the single-phase austenite (γ-Fe) region was studied under isothermal annealing conditions at temperatures of 1050 °C, 1150 °C, 1250 °C and 1350 °C. High-temperature laser scanning confocal microscopy (HT-LSCM) was used to observe and quantify in situ grain growth on the surface of three different samples containing 0.026 wt.-% P, 0.044 wt.-% P and 0.102 wt.-% P. The dependence of the arithmetic mean grain sizes on time and temperature were modeled mathematically using a simple ordinary differential equation (ODE) according to normal grain growth (NGG) theory. As no other major effects, i.e., Zener-pinning by precipitates, occurred under the selected experimental conditions, grain growth interference was only considered by grain boundary (GB) segregation of P. Thus, the total grain boundary mobility (M) was directly determined depending on the P content and isothermal annealing temperature. The fitted GB mobility values enabled the determination of an average binding energy value between impurity P atoms and grain boundaries (E0 = -1.1 - -0.6 eV) in the system. Finally, the GB segregation of P in γ-Fe was derived from the observed grain growth kinetics. The results showed reasonable agreement with calculations using segregation enthalpies from the literature.

U2 - 10.1016/j.actamat.2024.119826

DO - 10.1016/j.actamat.2024.119826

M3 - Article

VL - 269.2024

JO - Acta Materialia

JF - Acta Materialia

SN - 1359-6454

IS - 1 May

M1 - 119826

ER -