Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles

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Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles. / Summerer, Harald; Rath, Kirsten; Nenning, Andreas et al.
In: Journal of Materials Chemistry A, Vol. 12.2024, No. 31, 03.07.2024, p. 20386-20402.

Research output: Contribution to journalArticleResearchpeer-review

Harvard

Summerer, H, Rath, K, Nenning, A, Schachinger, T, Stöger-Pollach, M, Rameshan, C & Opitz, AK 2024, 'Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles', Journal of Materials Chemistry A, vol. 12.2024, no. 31, pp. 20386-20402. https://doi.org/10.1039/d4ta00989d

APA

Summerer, H., Rath, K., Nenning, A., Schachinger, T., Stöger-Pollach, M., Rameshan, C., & Opitz, A. K. (2024). Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles. Journal of Materials Chemistry A, 12.2024(31), 20386-20402. https://doi.org/10.1039/d4ta00989d

Vancouver

Summerer H, Rath K, Nenning A, Schachinger T, Stöger-Pollach M, Rameshan C et al. Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles. Journal of Materials Chemistry A. 2024 Jul 3;12.2024(31):20386-20402. doi: 10.1039/d4ta00989d

Author

Summerer, Harald ; Rath, Kirsten ; Nenning, Andreas et al. / Electro-tuned catalysts : voltage-controlled activity selection of bimetallic exsolution particles. In: Journal of Materials Chemistry A. 2024 ; Vol. 12.2024, No. 31. pp. 20386-20402.

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@article{54075c0782f0468c9a985a1efefaa79f,
title = "Electro-tuned catalysts: voltage-controlled activity selection of bimetallic exsolution particles",
abstract = "In this work, we show how the activity states of bimetallic Ni0-Fe0 catalysts exsolved from Nd0.6Ca0.4Fe0.97Ni0.03O3−δ (NCFNi) can be influenced electrochemically. The NCFNi parent oxide was employed in the form of thin film mixed conducting model electrodes, which were operated in a humid hydrogen atmosphere. By precisely controlling the oxygen chemical potential in the parent oxide electrode via applying an electrochemical polarisation, we managed to selectively exsolve Ni nanoparticles from the perovskite lattice and study their catalytic activity switching characteristics. To be able to track the surface chemical changes during the switching process, electrochemical polarisation experiments were combined with near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) measurements. This in situ analytical approach allowed relating the difference we observed in the switching behaviour of Ni particles here and of Fe particles in a recent study, to a different kinetic interplay between electrochemical driving force and atmosphere. We propose that slow oxygen transport through nickel oxide, located at the particle/perovskite interface, is mainly responsible for the observed difference to iron exsolutions, which becomes especially evident for larger nickel particles. In addition, in the case of bimetallic exsolutions and with applied bias voltage as a control parameter, we are able to reversibly switch between three different activity states, namely bimetallic Ni0-Fe0 (medium activity), pure Ni0 (high activity), and the inactive oxides.",
author = "Harald Summerer and Kirsten Rath and Andreas Nenning and Thomas Schachinger and Michael St{\"o}ger-Pollach and Christoph Rameshan and Opitz, {Alexander Karl}",
note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",
year = "2024",
month = jul,
day = "3",
doi = "10.1039/d4ta00989d",
language = "English",
volume = "12.2024",
pages = "20386--20402",
journal = "Journal of Materials Chemistry A",
issn = "2050-7488",
publisher = "Royal Society of Chemistry",
number = "31",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Electro-tuned catalysts

T2 - voltage-controlled activity selection of bimetallic exsolution particles

AU - Summerer, Harald

AU - Rath, Kirsten

AU - Nenning, Andreas

AU - Schachinger, Thomas

AU - Stöger-Pollach, Michael

AU - Rameshan, Christoph

AU - Opitz, Alexander Karl

N1 - Publisher Copyright: © 2024 The Royal Society of Chemistry.

PY - 2024/7/3

Y1 - 2024/7/3

N2 - In this work, we show how the activity states of bimetallic Ni0-Fe0 catalysts exsolved from Nd0.6Ca0.4Fe0.97Ni0.03O3−δ (NCFNi) can be influenced electrochemically. The NCFNi parent oxide was employed in the form of thin film mixed conducting model electrodes, which were operated in a humid hydrogen atmosphere. By precisely controlling the oxygen chemical potential in the parent oxide electrode via applying an electrochemical polarisation, we managed to selectively exsolve Ni nanoparticles from the perovskite lattice and study their catalytic activity switching characteristics. To be able to track the surface chemical changes during the switching process, electrochemical polarisation experiments were combined with near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) measurements. This in situ analytical approach allowed relating the difference we observed in the switching behaviour of Ni particles here and of Fe particles in a recent study, to a different kinetic interplay between electrochemical driving force and atmosphere. We propose that slow oxygen transport through nickel oxide, located at the particle/perovskite interface, is mainly responsible for the observed difference to iron exsolutions, which becomes especially evident for larger nickel particles. In addition, in the case of bimetallic exsolutions and with applied bias voltage as a control parameter, we are able to reversibly switch between three different activity states, namely bimetallic Ni0-Fe0 (medium activity), pure Ni0 (high activity), and the inactive oxides.

AB - In this work, we show how the activity states of bimetallic Ni0-Fe0 catalysts exsolved from Nd0.6Ca0.4Fe0.97Ni0.03O3−δ (NCFNi) can be influenced electrochemically. The NCFNi parent oxide was employed in the form of thin film mixed conducting model electrodes, which were operated in a humid hydrogen atmosphere. By precisely controlling the oxygen chemical potential in the parent oxide electrode via applying an electrochemical polarisation, we managed to selectively exsolve Ni nanoparticles from the perovskite lattice and study their catalytic activity switching characteristics. To be able to track the surface chemical changes during the switching process, electrochemical polarisation experiments were combined with near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) measurements. This in situ analytical approach allowed relating the difference we observed in the switching behaviour of Ni particles here and of Fe particles in a recent study, to a different kinetic interplay between electrochemical driving force and atmosphere. We propose that slow oxygen transport through nickel oxide, located at the particle/perovskite interface, is mainly responsible for the observed difference to iron exsolutions, which becomes especially evident for larger nickel particles. In addition, in the case of bimetallic exsolutions and with applied bias voltage as a control parameter, we are able to reversibly switch between three different activity states, namely bimetallic Ni0-Fe0 (medium activity), pure Ni0 (high activity), and the inactive oxides.

UR - http://www.scopus.com/inward/record.url?scp=85199009430&partnerID=8YFLogxK

U2 - 10.1039/d4ta00989d

DO - 10.1039/d4ta00989d

M3 - Article

AN - SCOPUS:85199009430

VL - 12.2024

SP - 20386

EP - 20402

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

SN - 2050-7488

IS - 31

ER -