Degradation of PET – Quantitative estimation of changes in molar mass using mechanical and thermal characterization methods
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In: Polymer Testing, Vol. 125.2023, No. August, 108130, 08.2023.
Research output: Contribution to journal › Article › Research › peer-review
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TY - JOUR
T1 - Degradation of PET – Quantitative estimation of changes in molar mass using mechanical and thermal characterization methods
AU - Oreski, Gernot
AU - Ottersböck, Bettina
AU - Barretta, Chiara
AU - Christöfl, Petra
AU - Radl, Simone
AU - Pinter, Gerald Gerhard
N1 - Funding Information: The research work was performed within the COMET-project „ Reliability of photovoltaivc system components“ (project-no.: 3.02) at the Polymer Competence Center Leoben GmbH (PCCL, Austria) within the framework of the COMET-program of the Federal Ministry for Climate Action, Environment, Energy, Mobility, Innovation and Technology and the Federal Ministry for Digital and Economic Affairs with contributions by the Chair of Material Science and Testing of Polymers at Montanuniversität Leoben. The PCCL is funded by the Austrian Government and the State Governments of Styria , Lower Austria and Upper Austria. Publisher Copyright: © 2023 The Author(s)
PY - 2023/8
Y1 - 2023/8
N2 - Polyethylene terephthalate (PET) films are used when mechanical strength, thermal and chemical stability, and barrier properties to atmospheric gases are required in combination with good processability. Hydrolysis leading to embrittlement of the material is a major concern as PET is used in a variety of applications with expected lifetimes of up to decades (e.g., for use in buildings, textiles, or photovoltaic backsheets). Therefore, a comprehensive understanding of the degradation processes and the effects on the molecular mass distribution is of great importance.Usually, the direct determination of molar mass and molar mass distribution involves high effort and sophisticated equipment. Therefore, the main objective of this work is to quantify molar mass changes due to accelerated aging using thermal and mechanical methods. Two stabilized PET films were subjected to seven different accelerated aging conditions (heat; combined heat-humidity). The samples were then characterized by size exclusion chromatography (SEC), tensile tests and differential scanning calorimetry (DSC).A linear correlation was found between crystallization temperature and average molar mass. The values of fracture stress from tensile tests indicate a ductile-brittle transition at a molar mass of 15 000 g mol−1. The study concludes that the crystallization temperature obtained from DSC measurements can be used to estimate changes in the average molar mass of PET after hydrolysis. Crystallization temperatures between 208 °C and 211 °C correspond to a critical reduction in molar mass and severe embrittlement.
AB - Polyethylene terephthalate (PET) films are used when mechanical strength, thermal and chemical stability, and barrier properties to atmospheric gases are required in combination with good processability. Hydrolysis leading to embrittlement of the material is a major concern as PET is used in a variety of applications with expected lifetimes of up to decades (e.g., for use in buildings, textiles, or photovoltaic backsheets). Therefore, a comprehensive understanding of the degradation processes and the effects on the molecular mass distribution is of great importance.Usually, the direct determination of molar mass and molar mass distribution involves high effort and sophisticated equipment. Therefore, the main objective of this work is to quantify molar mass changes due to accelerated aging using thermal and mechanical methods. Two stabilized PET films were subjected to seven different accelerated aging conditions (heat; combined heat-humidity). The samples were then characterized by size exclusion chromatography (SEC), tensile tests and differential scanning calorimetry (DSC).A linear correlation was found between crystallization temperature and average molar mass. The values of fracture stress from tensile tests indicate a ductile-brittle transition at a molar mass of 15 000 g mol−1. The study concludes that the crystallization temperature obtained from DSC measurements can be used to estimate changes in the average molar mass of PET after hydrolysis. Crystallization temperatures between 208 °C and 211 °C correspond to a critical reduction in molar mass and severe embrittlement.
KW - Critical molar mass
KW - Degradation
KW - DSC
KW - Hydrolysis
KW - Molar mass estimation
KW - PET
UR - http://www.scopus.com/inward/record.url?scp=85162749617&partnerID=8YFLogxK
U2 - 10.1016/j.polymertesting.2023.108130
DO - 10.1016/j.polymertesting.2023.108130
M3 - Article
AN - SCOPUS:85162749617
VL - 125.2023
JO - Polymer Testing
JF - Polymer Testing
SN - 0142-9418
IS - August
M1 - 108130
ER -