TY - THES

T1 - Chemical recycling of plastic waste via production of ethylene from gasification syngas

AU - Maier, Matthias

N1 - embargoed until 06-05-2025

PY - 2024

Y1 - 2024

N2 - A plastic waste to ethylene (PtE) process through steam-oxygen gasification, methanation and oxidative coupling of methane was investigated. Gasification was modelled using a stochastic reactor model, while the downstream process was modelled using Aspen Plus. This study investigated two cases, one with venting of captured CO2 and one with CO2 compression and transport. In addition, two alternative feedstocks and their effect on the process were explored.The model was evaluated from a technical, economic, and ecological perspective. For the ecological evaluation, the investigated plastic recycling process was compared to naphtha steam cracking, and it was found that 5.7-18.4 kgCO2eq/kg ethylene can be avoided. The minimum ethylene sales price was found using a discounted cashflow calculation and is between 4.9-5.4 €/kg. This leads to costs of CO2 avoided between 230-666 €/tCO2eq. Moreover, a sensitivity analysis on costs of CO2 avoided using 20,000 random parameter values was conducted.

AB - A plastic waste to ethylene (PtE) process through steam-oxygen gasification, methanation and oxidative coupling of methane was investigated. Gasification was modelled using a stochastic reactor model, while the downstream process was modelled using Aspen Plus. This study investigated two cases, one with venting of captured CO2 and one with CO2 compression and transport. In addition, two alternative feedstocks and their effect on the process were explored.The model was evaluated from a technical, economic, and ecological perspective. For the ecological evaluation, the investigated plastic recycling process was compared to naphtha steam cracking, and it was found that 5.7-18.4 kgCO2eq/kg ethylene can be avoided. The minimum ethylene sales price was found using a discounted cashflow calculation and is between 4.9-5.4 €/kg. This leads to costs of CO2 avoided between 230-666 €/tCO2eq. Moreover, a sensitivity analysis on costs of CO2 avoided using 20,000 random parameter values was conducted.

KW - Chemisches Recycling

KW - Dampf-Sauerstoff Vergasung

KW - Oxidative Kopplung von Methan

KW - Kosten von vermiedenem CO2

KW - Chemical recycling

KW - steam-oxygen gasification

KW - oxidative coupling of methane

KW - cost of CO2 avoided

U2 - 10.34901/mul.pub.2024.176

DO - 10.34901/mul.pub.2024.176

M3 - Master's Thesis

ER -