Ce nanoparticles and sol-gel hybrid organic-inorganic coatings maximize corrosion protection in the anodized AA2024-T3
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In: Corrosion science, Vol. 221.2023, No. 15 August, 111330, 15.08.2023.
Research output: Contribution to journal › Article › Research › peer-review
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TY - JOUR
T1 - Ce nanoparticles and sol-gel hybrid organic-inorganic coatings maximize corrosion protection in the anodized AA2024-T3
AU - Prada Ramirez, Oscar Mauricio
AU - Kremmer, Thomas
AU - Marin, J. H.
AU - da Silva, B. P.
AU - Starykevich, Maksim
AU - Tunes, Matheus
AU - Ferreira, Mário G.S.
AU - Aoki, I. V.
AU - Ando, R. A.
AU - Pogatscher, Stefan
AU - de Melo, Hercílio Gomes
N1 - Publisher Copyright: © 2023 Elsevier Ltd
PY - 2023/8/15
Y1 - 2023/8/15
N2 - We demonstrate that the corrosion resistance of the AA2024-T3 alloy can be maximized with the application of top protective sol-gel hybrid organic-inorganic coatings. Samples combining Ce nanoparticles within the pores of the anodic layer with the top sol-gel coatings were observed to outperform samples featuring only the coating. This research unravels the self-healing capability against corrosion of the sol-gel coating when Ce nanoparticles are present, as well as a good coverage of defective regions within the oxide by the hybrid layer. This research opens a paradigm aiming at maximizing the corrosion resistance for non-ferrous anodized alloys.
AB - We demonstrate that the corrosion resistance of the AA2024-T3 alloy can be maximized with the application of top protective sol-gel hybrid organic-inorganic coatings. Samples combining Ce nanoparticles within the pores of the anodic layer with the top sol-gel coatings were observed to outperform samples featuring only the coating. This research unravels the self-healing capability against corrosion of the sol-gel coating when Ce nanoparticles are present, as well as a good coverage of defective regions within the oxide by the hybrid layer. This research opens a paradigm aiming at maximizing the corrosion resistance for non-ferrous anodized alloys.
KW - Anodization
KW - Ce post-treatment
KW - Local electrochemical impedance spectroscopy
KW - Scanning Transmission Electron Microscopy
KW - Self-healing
KW - Sol-gel hybrid coating
UR - http://www.scopus.com/inward/record.url?scp=85162908659&partnerID=8YFLogxK
U2 - 10.1016/j.corsci.2023.111330
DO - 10.1016/j.corsci.2023.111330
M3 - Article
AN - SCOPUS:85162908659
VL - 221.2023
JO - Corrosion science
JF - Corrosion science
SN - 0010-938X
IS - 15 August
M1 - 111330
ER -