TY - JOUR

T1 - Black goes green

T2 - single-step solvent exchange for sol-gel synthesis of carbon spherogels as high-performance supercapacitor electrodes

AU - Salihovic, Miralem

AU - Pameté, Emmanuel

AU - Arnold, Stefanie

AU - Sulejmani, Irena

AU - Bartschmid, Theresa

AU - Hüsing, Nicola

AU - Fritz-Popovski, Gerhard

AU - Dun, Chaochao

AU - Urban, Jeffrey J.

AU - Presser, Volker

AU - Elsaesser, Michael S.

N1 - Publisher Copyright: © 2024 RSC.

PY - 2024/1/8

Y1 - 2024/1/8

N2 - Nanoporous carbon materials with customized structural features enable sustainable and electrochemical applications through improved performance and efficiency. Carbon spherogels (highly porous carbon aerogel materials consisting of an assembly of hollow carbon nanosphere units with uniform diameters) are desirable candidates as they combine exceptional electrical conductivity, bespoke shell porosity, tunability of the shell thickness, and a high surface area. Herein, we introduce a novel and more environmentally friendly sol-gel synthesis of resorcinol-formaldehyde (RF) templated by polystyrene spheres, forming carbon spherogels in an organic solvent. By tailoring the molar ratio of resorcinol to isopropyl alcohol (R/IPA) and the concentration of polystyrene, the appropriate synthesis conditions were identified to produce carbon spherogels with adjustable wall thicknesses. A single-step solvent exchange process from deionized water to isopropyl alcohol reduces surface tension within the porous gel network, making this approach significantly time and cost-effective. The lower surface tension of IPA enables solvent extraction under ambient conditions, allowing for direct carbonization of RF gels while maintaining a specific surface area loss of less than 20% compared to supercritically dried counterparts. The specific surface areas obtained after physical activation with carbon dioxide are 2300-3600 m2 g−1. Transmission and scanning electron microscopy verify the uniform, hollow carbon sphere network morphology. Specifically, those carbon spherogels are high-performing electrodes for energy storage in a supercapacitor setup featuring a specific capacitance of up to 204 F g−1 at 200 mA g−1 using 1 M potassium hydroxide (KOH) solution as the electrolyte.

AB - Nanoporous carbon materials with customized structural features enable sustainable and electrochemical applications through improved performance and efficiency. Carbon spherogels (highly porous carbon aerogel materials consisting of an assembly of hollow carbon nanosphere units with uniform diameters) are desirable candidates as they combine exceptional electrical conductivity, bespoke shell porosity, tunability of the shell thickness, and a high surface area. Herein, we introduce a novel and more environmentally friendly sol-gel synthesis of resorcinol-formaldehyde (RF) templated by polystyrene spheres, forming carbon spherogels in an organic solvent. By tailoring the molar ratio of resorcinol to isopropyl alcohol (R/IPA) and the concentration of polystyrene, the appropriate synthesis conditions were identified to produce carbon spherogels with adjustable wall thicknesses. A single-step solvent exchange process from deionized water to isopropyl alcohol reduces surface tension within the porous gel network, making this approach significantly time and cost-effective. The lower surface tension of IPA enables solvent extraction under ambient conditions, allowing for direct carbonization of RF gels while maintaining a specific surface area loss of less than 20% compared to supercritically dried counterparts. The specific surface areas obtained after physical activation with carbon dioxide are 2300-3600 m2 g−1. Transmission and scanning electron microscopy verify the uniform, hollow carbon sphere network morphology. Specifically, those carbon spherogels are high-performing electrodes for energy storage in a supercapacitor setup featuring a specific capacitance of up to 204 F g−1 at 200 mA g−1 using 1 M potassium hydroxide (KOH) solution as the electrolyte.

UR - http://www.scopus.com/inward/record.url?scp=85182882818&partnerID=8YFLogxK

U2 - 10.1039/d3ya00480e

DO - 10.1039/d3ya00480e

M3 - Article

AN - SCOPUS:85182882818

VL - 3.2024

SP - 482

EP - 494

JO - Energy Advances

JF - Energy Advances

IS - 2

ER -