Biobased Vitrimeric Epoxy Networks
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In: Macromolecular materials and engineering, Vol. 309.2024, No. 9, 2300371, 24.12.2023.
Research output: Contribution to journal › Review article › peer-review
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TY - JOUR
T1 - Biobased Vitrimeric Epoxy Networks
AU - Sangermano, Marco
AU - Bergoglio, Matteo
AU - Schlögl, Sandra
N1 - Publisher Copyright: © 2023 The Authors. Macromolecular Materials and Engineering published by Wiley-VCH GmbH.
PY - 2023/12/24
Y1 - 2023/12/24
N2 - The scientific strategies reported in the literature for developing biobased epoxy vitrimers are summarized. Biomass resources such as lignin, cellulose, or different vegetable oils can be exploited as biobased building blocks for epoxy thermosets as an alternative to the bisphenol-A-based ones. Biorenewable resources have been synthesized introducing dynamic covalent bonds in the cross-linked networks. This combination allows to achieve cross-linked biobased epoxy networks with thermoset-like properties at a temperature of use, but showing (re)processability, recyclability, and self-healing properties above a well-defined temperature named topology freezing transition temperature (Tv).
AB - The scientific strategies reported in the literature for developing biobased epoxy vitrimers are summarized. Biomass resources such as lignin, cellulose, or different vegetable oils can be exploited as biobased building blocks for epoxy thermosets as an alternative to the bisphenol-A-based ones. Biorenewable resources have been synthesized introducing dynamic covalent bonds in the cross-linked networks. This combination allows to achieve cross-linked biobased epoxy networks with thermoset-like properties at a temperature of use, but showing (re)processability, recyclability, and self-healing properties above a well-defined temperature named topology freezing transition temperature (Tv).
KW - biobased epoxy network
KW - epoxidized vegetable oils
KW - vitrimers
UR - http://www.scopus.com/inward/record.url?scp=85180487877&partnerID=8YFLogxK
U2 - 10.1002/mame.202300371
DO - 10.1002/mame.202300371
M3 - Review article
AN - SCOPUS:85180487877
VL - 309.2024
JO - Macromolecular materials and engineering
JF - Macromolecular materials and engineering
SN - 1438-7492
IS - 9
M1 - 2300371
ER -
