Surface science approach to Pt/carbon model catalysts: XPS, STM and microreactor studies

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

Autoren

  • Abdul Md Motin
  • Thomas Haunold
  • Andrey V. Bukhtiyarov
  • Abhijit Bera
  • Günther Rupprechter

Externe Organisationseinheiten

  • Technische Universität Wien
  • Boreskov Institute of Catalysis SB RAS
  • Midnapore College

Abstract

Pt nanoparticles supported on carbon are an important technological catalyst. A corresponding model catalyst was prepared by physical vapor deposition (PVD) of Pt on sputtered HOPG (highly oriented pyrolytic graphite). The carbon substrate before and after sputtering as well as the Pt/HOPG system before and after Pt deposition and annealing were examined by XPS and STM. This yielded information on the surface density of defects, which serve as nucleation centres for Pt, and on the size distribution (mean size/height) of the Pt nanoparticles. Two different model catalysts were prepared with mean sizes of 2.0 and 3.6 nm, both turned out to be stable upon UHV-annealing to 300 °C. After transfer into a UHV-compatible flow microreactor and subsequent cleaning in UHV and under mbar pressure, the catalytic activity of the Pt/HOPG model system for ethylene hydrogenation was examined under atmospheric pressure flow conditions. This enabled to determine temperature-dependent conversion rates, turnover frequencies (TOFs) and activation energies. The catalytic results obtained are in line with the characteristics of technological Pt/C, demonstrating the validity of the current surface science based model catalyst approach.

Details

OriginalspracheEnglisch
Seiten (von - bis)680-687
Seitenumfang8
FachzeitschriftApplied surface science
Jahrgang440.2018
Ausgabenummer15 May
DOIs
StatusElektronische Veröffentlichung vor Drucklegung. - 31 Jan. 2018
Extern publiziertJa