Performance modulation through selective, homogenous surface doping of lanthanum strontium ferrite electrodes revealed by: In situ PLD impedance measurements
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in: Journal of Materials Chemistry A, Jahrgang 10.2022, Nr. 6, 14.02.2022, S. 2973-2986.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
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TY - JOUR
T1 - Performance modulation through selective, homogenous surface doping of lanthanum strontium ferrite electrodes revealed by
T2 - In situ PLD impedance measurements
AU - Riedl, Christoph
AU - Siebenhofer, Matthäus
AU - Nenning, Andreas
AU - Friedbacher, Gernot
AU - Weiss, Maximilian
AU - Rameshan, Christoph
AU - Bernardi, Johannes
AU - Limbeck, Andreas
AU - Kubicek, Markus
AU - Opitz, Alexander Karl
AU - Fleig, Juergen
N1 - Publisher Copyright: © 2022 The Royal Society of Chemistry.
PY - 2022/2/14
Y1 - 2022/2/14
N2 - Accelerating the oxygen reduction kinetics of solid oxide fuel cell (SOFC) cathodes is crucial to improve their efficiency and thus to provide the basis for an economically feasible application of intermediate temperature SOFCs. In this work, minor amounts of Pt were doped into lanthanum strontium ferrite (LSF) thin film electrodes to modulate the material's oxygen exchange performance. Surprisingly, Pt was found to be incorporated on the B-site of the perovskite electrode as non metallic Pt4+. The polarization resistance of LSF thin film electrodes with and without additional Pt surface doping was compared directly after film growth employing in situ electrochemical impedance spectroscopy inside a PLD chamber (i-PLD). This technique enables observation of the polarization resistance of pristine electrodes unaltered by degradation or any external contamination of the electrode surface. Moreover, growth of multi-layers of materials with different compositions on the very same single crystalline electrolyte substrate combined with in situ impedance measurements allow excellent comparability of different materials. Even a 5 nm layer of Pt doped LSF (1.5 at% Pt), i.e. a Pt loading of 80 ng cm−2, improved the polarization resistance by a factor of about 2.5. In addition, p(O2) and temperature dependent impedance measurements on both pure and Pt doped LSF were performed in situ and obtained similar activation energies and p(O2) dependence of the polarization resistance, which allow us to make far reaching mechanistic conclusions indicating that Pt4+ introduces additional active sites.
AB - Accelerating the oxygen reduction kinetics of solid oxide fuel cell (SOFC) cathodes is crucial to improve their efficiency and thus to provide the basis for an economically feasible application of intermediate temperature SOFCs. In this work, minor amounts of Pt were doped into lanthanum strontium ferrite (LSF) thin film electrodes to modulate the material's oxygen exchange performance. Surprisingly, Pt was found to be incorporated on the B-site of the perovskite electrode as non metallic Pt4+. The polarization resistance of LSF thin film electrodes with and without additional Pt surface doping was compared directly after film growth employing in situ electrochemical impedance spectroscopy inside a PLD chamber (i-PLD). This technique enables observation of the polarization resistance of pristine electrodes unaltered by degradation or any external contamination of the electrode surface. Moreover, growth of multi-layers of materials with different compositions on the very same single crystalline electrolyte substrate combined with in situ impedance measurements allow excellent comparability of different materials. Even a 5 nm layer of Pt doped LSF (1.5 at% Pt), i.e. a Pt loading of 80 ng cm−2, improved the polarization resistance by a factor of about 2.5. In addition, p(O2) and temperature dependent impedance measurements on both pure and Pt doped LSF were performed in situ and obtained similar activation energies and p(O2) dependence of the polarization resistance, which allow us to make far reaching mechanistic conclusions indicating that Pt4+ introduces additional active sites.
UR - http://www.scopus.com/inward/record.url?scp=85124616221&partnerID=8YFLogxK
U2 - 10.1039/d1ta08634k
DO - 10.1039/d1ta08634k
M3 - Article
AN - SCOPUS:85124616221
VL - 10.2022
SP - 2973
EP - 2986
JO - Journal of Materials Chemistry A
JF - Journal of Materials Chemistry A
SN - 2050-7488
IS - 6
ER -