TY - JOUR

T1 - Mapping the mechanical properties in nitride coatings at the nanometer scale

AU - Zhang, Zaoli

AU - Chen, Zhuo

AU - Holec, David

AU - Liebscher, Christian

AU - Koutná, Nikola

AU - Bartosik, Matthias

AU - Zheng, Yong Hui

AU - Dehm, Gerhard

AU - Mayrhofer, Paul Heinz

N1 - Publisher Copyright: © 2020 Acta Materialia Inc.

PY - 2020/8/1

Y1 - 2020/8/1

N2 - We report on a multilayered structure comprising of rock-salt (rs) structured CrN layers of constant thickness and AlN layers of varying thicknesses, which surprisingly enables the growth of metastable zinc-blende (zb) AlN layers for certain layer-thickness combinations. The multilayer exhibits an atomic and electronic structure gradient as revealed using advanced electron microscopy and electron spectroscopy. Gradient structures are also accompanied by a modulation of the chemical compositions. A combined experimental analysis based on valence electrons and inner shell electrons allowed mapping the mechanical properties of the multilayer at the nanometer scale and further unveiled the effect of oxygen impurities on the bulk modulus. We found that the presence of oxygen impurities causes a remarkable reduction of the bulk modulus of rs-CrN while having no significant effect on the bulk modulus of the stable wurtzite structure wz-AlN layers. The findings are unambiguously validated by theoretical calculations using density functional theory.

AB - We report on a multilayered structure comprising of rock-salt (rs) structured CrN layers of constant thickness and AlN layers of varying thicknesses, which surprisingly enables the growth of metastable zinc-blende (zb) AlN layers for certain layer-thickness combinations. The multilayer exhibits an atomic and electronic structure gradient as revealed using advanced electron microscopy and electron spectroscopy. Gradient structures are also accompanied by a modulation of the chemical compositions. A combined experimental analysis based on valence electrons and inner shell electrons allowed mapping the mechanical properties of the multilayer at the nanometer scale and further unveiled the effect of oxygen impurities on the bulk modulus. We found that the presence of oxygen impurities causes a remarkable reduction of the bulk modulus of rs-CrN while having no significant effect on the bulk modulus of the stable wurtzite structure wz-AlN layers. The findings are unambiguously validated by theoretical calculations using density functional theory.

UR - http://www.scopus.com/inward/record.url?scp=85085733000&partnerID=8YFLogxK

U2 - 10.1016/j.actamat.2020.04.024

DO - 10.1016/j.actamat.2020.04.024

M3 - Article

VL - 194.2020

SP - 343

EP - 353

JO - Acta materialia

JF - Acta materialia

SN - 1359-6454

IS - 1 August

ER -