Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

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Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators. / Maier, Janine; Müller, Stefanie M.; Torvisco, Ana et al.
in: ChemPhotoChem , Jahrgang 6.2022, Nr. 3, e202100213, 15.11.2021.

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

Harvard

Maier, J, Müller, SM, Torvisco, A, Glotz, G, Fischer, RC, Griesser, T, Kelterer, AM & Haas, M 2021, 'Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators', ChemPhotoChem , Jg. 6.2022, Nr. 3, e202100213. https://doi.org/10.1002/cptc.202100213

APA

Maier, J., Müller, S. M., Torvisco, A., Glotz, G., Fischer, R. C., Griesser, T., Kelterer, A. M., & Haas, M. (2021). Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators. ChemPhotoChem , 6.2022(3), Artikel e202100213. Vorzeitige Online-Publikation. https://doi.org/10.1002/cptc.202100213

Vancouver

Maier J, Müller SM, Torvisco A, Glotz G, Fischer RC, Griesser T et al. Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators. ChemPhotoChem . 2021 Nov 15;6.2022(3):e202100213. Epub 2021 Nov 15. doi: 10.1002/cptc.202100213

Author

Maier, Janine ; Müller, Stefanie M. ; Torvisco, Ana et al. / Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators. in: ChemPhotoChem . 2021 ; Jahrgang 6.2022, Nr. 3.

Bibtex - Download

@article{3bf8709440f745bab6124fe8c0daa981,
title = "Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators",
abstract = "Isolable stannenolates LKSn[(CO)R]3 (R=2,4,6-trimethylphenyl (1 a, b), L=DME for (1 a) or 18-crown-6 for (1 b)), a new building block for the synthesis of effective Sn-based photoinitiators, were synthesized. The formation of these derivatives was confirmed by NMR spectroscopy, UV/Vis spectroscopy as well as X-ray crystallographic analysis. Compound 1 a is employed as a synthon in main group chemistry through reactions with two different types of electrophiles (acid chlorides and alkyl halides). All investigated electrophiles react via the salt metathesis reaction and gave rise to novel acylstannanes in good to excellent yields. The applicability as visible light photoinitiators is demonstrated by photobleaching (UV/Vis absorption spectroscopic studies) as well as through application in photo-DSC studies.",
keywords = "acylstannanes, organostannanes, photoinitiators, radical polymerization, stannenolates",
author = "Janine Maier and M{\"u}ller, {Stefanie M.} and Ana Torvisco and Gabriel Glotz and Fischer, {Roland C.} and Thomas Griesser and Kelterer, {Anne Marie} and Michael Haas",
note = "Publisher Copyright: {\textcopyright} 2021 The Authors. ChemPhotoChem published by Wiley-VCH GmbH",
year = "2021",
month = nov,
day = "15",
doi = "10.1002/cptc.202100213",
language = "English",
volume = "6.2022",
journal = "ChemPhotoChem ",
issn = "2367-0932",
publisher = "Wiley-VCH ",
number = "3",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Isolable Stannenolates Enable the Synthesis of Visible-Light Photoinitiators

AU - Maier, Janine

AU - Müller, Stefanie M.

AU - Torvisco, Ana

AU - Glotz, Gabriel

AU - Fischer, Roland C.

AU - Griesser, Thomas

AU - Kelterer, Anne Marie

AU - Haas, Michael

N1 - Publisher Copyright: © 2021 The Authors. ChemPhotoChem published by Wiley-VCH GmbH

PY - 2021/11/15

Y1 - 2021/11/15

N2 - Isolable stannenolates LKSn[(CO)R]3 (R=2,4,6-trimethylphenyl (1 a, b), L=DME for (1 a) or 18-crown-6 for (1 b)), a new building block for the synthesis of effective Sn-based photoinitiators, were synthesized. The formation of these derivatives was confirmed by NMR spectroscopy, UV/Vis spectroscopy as well as X-ray crystallographic analysis. Compound 1 a is employed as a synthon in main group chemistry through reactions with two different types of electrophiles (acid chlorides and alkyl halides). All investigated electrophiles react via the salt metathesis reaction and gave rise to novel acylstannanes in good to excellent yields. The applicability as visible light photoinitiators is demonstrated by photobleaching (UV/Vis absorption spectroscopic studies) as well as through application in photo-DSC studies.

AB - Isolable stannenolates LKSn[(CO)R]3 (R=2,4,6-trimethylphenyl (1 a, b), L=DME for (1 a) or 18-crown-6 for (1 b)), a new building block for the synthesis of effective Sn-based photoinitiators, were synthesized. The formation of these derivatives was confirmed by NMR spectroscopy, UV/Vis spectroscopy as well as X-ray crystallographic analysis. Compound 1 a is employed as a synthon in main group chemistry through reactions with two different types of electrophiles (acid chlorides and alkyl halides). All investigated electrophiles react via the salt metathesis reaction and gave rise to novel acylstannanes in good to excellent yields. The applicability as visible light photoinitiators is demonstrated by photobleaching (UV/Vis absorption spectroscopic studies) as well as through application in photo-DSC studies.

KW - acylstannanes

KW - organostannanes

KW - photoinitiators

KW - radical polymerization

KW - stannenolates

UR - http://www.scopus.com/inward/record.url?scp=85120453390&partnerID=8YFLogxK

U2 - 10.1002/cptc.202100213

DO - 10.1002/cptc.202100213

M3 - Article

AN - SCOPUS:85120453390

VL - 6.2022

JO - ChemPhotoChem

JF - ChemPhotoChem

SN - 2367-0932

IS - 3

M1 - e202100213

ER -