Investigating Photocurable Thiol-Yne Resins for Biomedical Materials

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Investigating Photocurable Thiol-Yne Resins for Biomedical Materials. / Oesterreicher, Andreas; Moser, Andreas; Edler, Matthias et al.
in: Macromolecular materials and engineering, Jahrgang 302.2017, Nr. 5, 1600450, 2017.

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

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@article{d6d8b8b7b7f7466980fe7369ecbca8be,
title = "Investigating Photocurable Thiol-Yne Resins for Biomedical Materials",
abstract = "This study deals with the investigation of photocurable thiol-yne resins covering several important aspects for the production of medical devices by UV-based manufacturing processes. In this context, the performance of different low-toxic photoinitiators (PIs) and stabilizers are evaluated in thiol-yne formulations based on di(but-1-yn-4-yl) carbonate and various multifunctional thiol monomers. Photodifferential scanning calorimetry measurements reveal that the conversion of all resin formulations is mostly independent on the type and concentration of the applied photoinitiator; however, significant differences in their curing speed are observed. It turns out that the migration of an alkyne derivatized photoinitiator is significantly reduced while providing almost similar photoactivity as its nonfunctionalized reference. Moreover, it is found that lauryl gallate and butylated hydroxytoluene lead to significant stabilization without affecting the overall photoreactivity. Notably, the thermomechanical properties of the investigated photopolymers are only slightly affected by water absorption. Using ester free thiols, water absorption can be reduced and hydrolytically stable polymers are realized. These results highlight the versatility of the present thiol-yne system for the production of medical materials by photopolymerization.",
keywords = "Thiol-in, biomedizinische Materialien, UV-Harze",
author = "Andreas Oesterreicher and Andreas Moser and Matthias Edler and Heidi Griesser and Sandra Schl{\"o}gl and Margit Pichelmayer and Thomas Grie{\ss}er",
year = "2017",
doi = "10.1002/mame.201600450",
language = "English",
volume = "302.2017",
journal = "Macromolecular materials and engineering",
issn = "1438-7492",
publisher = "Wiley-VCH ",
number = "5",

}

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TY - JOUR

T1 - Investigating Photocurable Thiol-Yne Resins for Biomedical Materials

AU - Oesterreicher, Andreas

AU - Moser, Andreas

AU - Edler, Matthias

AU - Griesser, Heidi

AU - Schlögl, Sandra

AU - Pichelmayer, Margit

AU - Grießer, Thomas

PY - 2017

Y1 - 2017

N2 - This study deals with the investigation of photocurable thiol-yne resins covering several important aspects for the production of medical devices by UV-based manufacturing processes. In this context, the performance of different low-toxic photoinitiators (PIs) and stabilizers are evaluated in thiol-yne formulations based on di(but-1-yn-4-yl) carbonate and various multifunctional thiol monomers. Photodifferential scanning calorimetry measurements reveal that the conversion of all resin formulations is mostly independent on the type and concentration of the applied photoinitiator; however, significant differences in their curing speed are observed. It turns out that the migration of an alkyne derivatized photoinitiator is significantly reduced while providing almost similar photoactivity as its nonfunctionalized reference. Moreover, it is found that lauryl gallate and butylated hydroxytoluene lead to significant stabilization without affecting the overall photoreactivity. Notably, the thermomechanical properties of the investigated photopolymers are only slightly affected by water absorption. Using ester free thiols, water absorption can be reduced and hydrolytically stable polymers are realized. These results highlight the versatility of the present thiol-yne system for the production of medical materials by photopolymerization.

AB - This study deals with the investigation of photocurable thiol-yne resins covering several important aspects for the production of medical devices by UV-based manufacturing processes. In this context, the performance of different low-toxic photoinitiators (PIs) and stabilizers are evaluated in thiol-yne formulations based on di(but-1-yn-4-yl) carbonate and various multifunctional thiol monomers. Photodifferential scanning calorimetry measurements reveal that the conversion of all resin formulations is mostly independent on the type and concentration of the applied photoinitiator; however, significant differences in their curing speed are observed. It turns out that the migration of an alkyne derivatized photoinitiator is significantly reduced while providing almost similar photoactivity as its nonfunctionalized reference. Moreover, it is found that lauryl gallate and butylated hydroxytoluene lead to significant stabilization without affecting the overall photoreactivity. Notably, the thermomechanical properties of the investigated photopolymers are only slightly affected by water absorption. Using ester free thiols, water absorption can be reduced and hydrolytically stable polymers are realized. These results highlight the versatility of the present thiol-yne system for the production of medical materials by photopolymerization.

KW - Thiol-in

KW - biomedizinische Materialien

KW - UV-Harze

U2 - 10.1002/mame.201600450

DO - 10.1002/mame.201600450

M3 - Article

VL - 302.2017

JO - Macromolecular materials and engineering

JF - Macromolecular materials and engineering

SN - 1438-7492

IS - 5

M1 - 1600450

ER -