Hybrid In Situ Reinforcement of EPDM Rubber Compounds Based on Phenolic Novolac Resin and Ionic Coagent
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in: Applied Sciences : open access journal, Jahrgang 12.2022, Nr. 5, 2432, 25.02.2022.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
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TY - JOUR
T1 - Hybrid In Situ Reinforcement of EPDM Rubber Compounds Based on Phenolic Novolac Resin and Ionic Coagent
AU - Strohmeier, Lara
AU - Balasooriya, Winoj
AU - Schrittesser, Bernd
AU - van Duin, Martin
AU - Schlögl, Sandra
N1 - Publisher Copyright: © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
PY - 2022/2/25
Y1 - 2022/2/25
N2 - For the design of stretchable and flexible high-performing materials, the reinforcement of elastomeric grades plays a crucial role. State-of-the-art fillers such as carbon black benefit from a high reinforcement but often negatively affect the processing and mixing properties of rubber compounds. To overcome this drawback, the synergistic properties of hybrid in situ filler systems are studied for EPDM compounds comprising a phenol novolac resin and ionic coagents such as zinc (meth)acrylates (ZD(M)A. With the help of a combined novolac/ZD(M)A system, the compounds could be tailored in a unique way towards higher toughness and enhanced cross-link density. Further, the fracture surface of the EPDM–novolac compounds was analyzed by scanning electron microscopy, revealing a significant change of the morphology from rough and disordered to smooth and homogenous for samples with coagents. In addition, the results clearly showed that the introduction of ionic coagents is able to compensate shares of carbon black filler in the EPDM compound. The toughening of samples with zinc (meth)acrylates is attributed to the synergistic formation of an interpenetrating polymer-filler network by simultaneous covalent and ionic cross-linking.
AB - For the design of stretchable and flexible high-performing materials, the reinforcement of elastomeric grades plays a crucial role. State-of-the-art fillers such as carbon black benefit from a high reinforcement but often negatively affect the processing and mixing properties of rubber compounds. To overcome this drawback, the synergistic properties of hybrid in situ filler systems are studied for EPDM compounds comprising a phenol novolac resin and ionic coagents such as zinc (meth)acrylates (ZD(M)A. With the help of a combined novolac/ZD(M)A system, the compounds could be tailored in a unique way towards higher toughness and enhanced cross-link density. Further, the fracture surface of the EPDM–novolac compounds was analyzed by scanning electron microscopy, revealing a significant change of the morphology from rough and disordered to smooth and homogenous for samples with coagents. In addition, the results clearly showed that the introduction of ionic coagents is able to compensate shares of carbon black filler in the EPDM compound. The toughening of samples with zinc (meth)acrylates is attributed to the synergistic formation of an interpenetrating polymer-filler network by simultaneous covalent and ionic cross-linking.
KW - Coagent
KW - In situ reinforcement
KW - Interpenetrating network
KW - Ionic cross-linking
KW - Resin
KW - Rubber compound
UR - http://www.scopus.com/inward/record.url?scp=85125790137&partnerID=8YFLogxK
U2 - 10.3390/app12052432
DO - 10.3390/app12052432
M3 - Article
AN - SCOPUS:85125790137
VL - 12.2022
JO - Applied Sciences : open access journal
JF - Applied Sciences : open access journal
SN - 2076-3417
IS - 5
M1 - 2432
ER -