How reduction temperature influences the structure of perovskite-oxide catalysts during the dry reforming of methane
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
Standard
in: RSC sustainability, Jahrgang 2024, Nr. 11, 10.10.2024, S. 3334-3344.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
Harvard
APA
Vancouver
Author
Bibtex - Download
}
RIS (suitable for import to EndNote) - Download
TY - JOUR
T1 - How reduction temperature influences the structure of perovskite-oxide catalysts during the dry reforming of methane
AU - Schrenk, Florian
AU - Lindenthal, Lorenz
AU - Drexler, Hedda
AU - Berger, Tobias
AU - Rameshan, Raffael
AU - Ruh, Thomas
AU - Föttinger, Karin
AU - Rameshan, Christoph
N1 - Publisher Copyright: © 2024 RSC.
PY - 2024/10/10
Y1 - 2024/10/10
N2 - Dry reforming of methane is a promising reaction to convert CO2 and combat climate change. However, the reaction is still not feasible in large-scale industrial applications. The thermodynamic need for high temperatures and the potential of carbon deposition leads to high requirements for potential catalyst materials. As shown in previous publications, the Ni-doped perovskite-oxide Nd0.6Ca0.4Fe0.97Ni0.03O3 is a potential candidate as it can exsolve highly active Ni nanoparticles on its surface. This study focused on controlling the particle size by varying the reduction temperature. We found the optimal temperature that allows the Ni nanoparticles to exsolve while not yet enabling the formation of deactivating CaCO3. Furthermore, the exsolution process and the behaviour of the phases during the dry reforming of methane were investigated using in situ XRD measurements at the DESY beamline P02.1 at PETRA III in Hamburg. They revealed that the formed deactivated phases would, at high temperatures, form a brownmillerite phase, thus hinting at a potential self-healing mechanism of these materials.
AB - Dry reforming of methane is a promising reaction to convert CO2 and combat climate change. However, the reaction is still not feasible in large-scale industrial applications. The thermodynamic need for high temperatures and the potential of carbon deposition leads to high requirements for potential catalyst materials. As shown in previous publications, the Ni-doped perovskite-oxide Nd0.6Ca0.4Fe0.97Ni0.03O3 is a potential candidate as it can exsolve highly active Ni nanoparticles on its surface. This study focused on controlling the particle size by varying the reduction temperature. We found the optimal temperature that allows the Ni nanoparticles to exsolve while not yet enabling the formation of deactivating CaCO3. Furthermore, the exsolution process and the behaviour of the phases during the dry reforming of methane were investigated using in situ XRD measurements at the DESY beamline P02.1 at PETRA III in Hamburg. They revealed that the formed deactivated phases would, at high temperatures, form a brownmillerite phase, thus hinting at a potential self-healing mechanism of these materials.
UR - http://www.scopus.com/inward/record.url?scp=85206656677&partnerID=8YFLogxK
U2 - 10.1039/d4su00483c
DO - 10.1039/d4su00483c
M3 - Article
AN - SCOPUS:85206656677
VL - 2024
SP - 3334
EP - 3344
JO - RSC sustainability
JF - RSC sustainability
SN - 2753-8125
IS - 11
ER -