Flow behavior of PP‐polymer nanocomposites in injection molding hyperbolical dies

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Flow behavior of PP‐polymer nanocomposites in injection molding hyperbolical dies. / Mitsoulis, Evan; Battisti, Markus; Neunhäuserer, Andreas et al.
in: Advances in Polymer Technology, Jahrgang 37.2018, Nr. 8, 24.04.2018, S. 3045-3055.

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

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Mitsoulis, Evan ; Battisti, Markus ; Neunhäuserer, Andreas et al. / Flow behavior of PP‐polymer nanocomposites in injection molding hyperbolical dies. in: Advances in Polymer Technology. 2018 ; Jahrgang 37.2018, Nr. 8. S. 3045-3055.

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@article{ab4d930750174a0ab65bd9eac559a283,
title = "Flow behavior of PP‐polymer nanocomposites in injection molding hyperbolical dies",
abstract = "Nanocomposites based on layered silicates offer a remarkable potential in improving mechanical properties with filler loadings lower than 5%. For such polymer nanocomposites, it is important to improve intercalation and exfoliation of the silicate layers by finding the right balance between these effects. Previous works showed that intercalation and exfoliation can be influenced by the use of an additional, extensional flow which can be generated by hyperbolical dies used in the injection molding process. Since such hyperbolical dies account for high shear rates, additional pressure drop, and viscous dissipation, it is of high practical relevance to correctly predict the injection pressure needed. Besides conical geometries, hyperbolical die geometries are of importance due to their uniform elongational rate. Using hyperbolical dies having different diameters, D, and length‐to‐diameter L/D ratios, a full rheological characterization has been carried out for a polypropylene‐filled nanocomposite, and the experimental data have been fitted both with a viscous model (Cross) and a viscoelastic one (the Kaye—Bernstein, Kearsley, Zapas/Papanastasiou, Scriven, Macosko or K‐BKZ/PSM model). Four injection molding dies have been also used to reach apparent shear rates up to 500,000 s−1. Particular emphasis has been given on the pressure dependence of viscosity. It was found that only the viscoelastic simulations were capable of reproducing the experimental data well, while any viscous modeling always underestimates the pressures, especially at the higher apparent shear rates and L/D ratios. ",
author = "Evan Mitsoulis and Markus Battisti and Andreas Neunh{\"a}userer and Leonhard Perko and Walter Friesenbichler",
year = "2018",
month = apr,
day = "24",
doi = "10.1002/adv.21975",
language = "English",
volume = "37.2018",
pages = "3045--3055",
journal = "Advances in Polymer Technology",
issn = "0730-6679",
publisher = "Wiley-Blackwell, USA",
number = "8",

}

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TY - JOUR

T1 - Flow behavior of PP‐polymer nanocomposites in injection molding hyperbolical dies

AU - Mitsoulis, Evan

AU - Battisti, Markus

AU - Neunhäuserer, Andreas

AU - Perko, Leonhard

AU - Friesenbichler, Walter

PY - 2018/4/24

Y1 - 2018/4/24

N2 - Nanocomposites based on layered silicates offer a remarkable potential in improving mechanical properties with filler loadings lower than 5%. For such polymer nanocomposites, it is important to improve intercalation and exfoliation of the silicate layers by finding the right balance between these effects. Previous works showed that intercalation and exfoliation can be influenced by the use of an additional, extensional flow which can be generated by hyperbolical dies used in the injection molding process. Since such hyperbolical dies account for high shear rates, additional pressure drop, and viscous dissipation, it is of high practical relevance to correctly predict the injection pressure needed. Besides conical geometries, hyperbolical die geometries are of importance due to their uniform elongational rate. Using hyperbolical dies having different diameters, D, and length‐to‐diameter L/D ratios, a full rheological characterization has been carried out for a polypropylene‐filled nanocomposite, and the experimental data have been fitted both with a viscous model (Cross) and a viscoelastic one (the Kaye—Bernstein, Kearsley, Zapas/Papanastasiou, Scriven, Macosko or K‐BKZ/PSM model). Four injection molding dies have been also used to reach apparent shear rates up to 500,000 s−1. Particular emphasis has been given on the pressure dependence of viscosity. It was found that only the viscoelastic simulations were capable of reproducing the experimental data well, while any viscous modeling always underestimates the pressures, especially at the higher apparent shear rates and L/D ratios.

AB - Nanocomposites based on layered silicates offer a remarkable potential in improving mechanical properties with filler loadings lower than 5%. For such polymer nanocomposites, it is important to improve intercalation and exfoliation of the silicate layers by finding the right balance between these effects. Previous works showed that intercalation and exfoliation can be influenced by the use of an additional, extensional flow which can be generated by hyperbolical dies used in the injection molding process. Since such hyperbolical dies account for high shear rates, additional pressure drop, and viscous dissipation, it is of high practical relevance to correctly predict the injection pressure needed. Besides conical geometries, hyperbolical die geometries are of importance due to their uniform elongational rate. Using hyperbolical dies having different diameters, D, and length‐to‐diameter L/D ratios, a full rheological characterization has been carried out for a polypropylene‐filled nanocomposite, and the experimental data have been fitted both with a viscous model (Cross) and a viscoelastic one (the Kaye—Bernstein, Kearsley, Zapas/Papanastasiou, Scriven, Macosko or K‐BKZ/PSM model). Four injection molding dies have been also used to reach apparent shear rates up to 500,000 s−1. Particular emphasis has been given on the pressure dependence of viscosity. It was found that only the viscoelastic simulations were capable of reproducing the experimental data well, while any viscous modeling always underestimates the pressures, especially at the higher apparent shear rates and L/D ratios.

U2 - 10.1002/adv.21975

DO - 10.1002/adv.21975

M3 - Article

VL - 37.2018

SP - 3045

EP - 3055

JO - Advances in Polymer Technology

JF - Advances in Polymer Technology

SN - 0730-6679

IS - 8

ER -