Evaluation of CLSM measurements for dissolution studies: A case study investigating alumina dissolution in a silicate slag
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in: Ceramics International, Jahrgang 48.2022, Nr. 19 Part A, 14.06.2022, S. 28174-28180.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
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TY - JOUR
T1 - Evaluation of CLSM measurements for dissolution studies
T2 - A case study investigating alumina dissolution in a silicate slag
AU - Harmuth, Harald
AU - Burhanuddin, Burhanuddin
N1 - Publisher Copyright: © 2022 Elsevier Ltd and Techna Group S.r.l.
PY - 2022/6/14
Y1 - 2022/6/14
N2 - Several approaches to evaluate confocal laser scanning microscopy (CLSM) investigations for high-temperature dissolution studies with the aim of determining effective binary diffusivities are reviewed here. Limitations of the existing approaches render their application for accurate quantification of diffusion-controlled dissolution. Existing approaches are modified to correctly consider the contribution of the Stefan flow. A new approach that can account for fluid motion and bridge the gap to a stagnant flow is proposed. The new approach is compared with the existing approaches and their corresponding modifications. The new approach is also compared with rotating finger tests in the case of alumina dissolution in a silicate slag. The new approach shows a superior performance and agrees well with the finger test results.
AB - Several approaches to evaluate confocal laser scanning microscopy (CLSM) investigations for high-temperature dissolution studies with the aim of determining effective binary diffusivities are reviewed here. Limitations of the existing approaches render their application for accurate quantification of diffusion-controlled dissolution. Existing approaches are modified to correctly consider the contribution of the Stefan flow. A new approach that can account for fluid motion and bridge the gap to a stagnant flow is proposed. The new approach is compared with the existing approaches and their corresponding modifications. The new approach is also compared with rotating finger tests in the case of alumina dissolution in a silicate slag. The new approach shows a superior performance and agrees well with the finger test results.
UR - http://www.scopus.com/inward/record.url?scp=85132511555&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2022.06.120
DO - 10.1016/j.ceramint.2022.06.120
M3 - Article
VL - 48.2022
SP - 28174
EP - 28180
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 19 Part A
ER -
