Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity

Research output: Contribution to journal › Article › Research › peer-review

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Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity. / Sarac, Baran; Zadorozhnyy, Vladislav; Ivanov, Yurii P. et al.
In: Corrosion science, Vol. 193.2021, No. December, 109880, 12.2021.

Research output: Contribution to journal › Article › Research › peer-review

Harvard

Sarac, B, Zadorozhnyy, V, Ivanov, YP, Spieckermann, F, Klyamkin, S, Berdonosova, E, Serov, M, Kaloshkin, S, Greer, AL, Sarac, AS & Eckert, J 2021, 'Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity', Corrosion science, vol. 193.2021, no. December, 109880. https://doi.org/10.1016/j.corsci.2021.109880

APA

Sarac, B., Zadorozhnyy, V., Ivanov, Y. P., Spieckermann, F., Klyamkin, S., Berdonosova, E., Serov, M., Kaloshkin, S., Greer, A. L., Sarac, A. S., & Eckert, J. (2021). Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity. Corrosion science, 193.2021(December), Article 109880. https://doi.org/10.1016/j.corsci.2021.109880

Vancouver

Sarac B, Zadorozhnyy V, Ivanov YP, Spieckermann F, Klyamkin S, Berdonosova E et al. Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity. Corrosion science. 2021 Dec;193.2021(December):109880. Epub 2021 Oct 12. doi: 10.1016/j.corsci.2021.109880

Author

Sarac, Baran ; Zadorozhnyy, Vladislav ; Ivanov, Yurii P. et al. / Transition metal-based high entropy alloy microfiber electrodes : Corrosion behavior and hydrogen activity. In: Corrosion science. 2021 ; Vol. 193.2021, No. December.

Bibtex - Download

@article{d00f497a63a44764aa8e240e44fcab2f,
title = "Transition metal-based high entropy alloy microfiber electrodes: Corrosion behavior and hydrogen activity",
abstract = "This contribution reveals ultra-high corrosion resistance of high entropy alloys (HEAs), i.e. Ti20Zr20Nb15V15Hf15Ta15 of 1.85 µm yr–1 in alkaline environment, adverting their use for battery/fuel cell components. Formation of several nanometers passive oxide layer confirmed by scanning transmission electron microscopy accounts for corrosion resistance which increases with TiOx content. Cathodic Tafel slope of 67 mV dec–1 and large transfer coefficient of 0.82 obtained for Ti20Zr20Nb20V20Ta20 suggest its use for hydrogen electrocatalysis. High amounts of hydrogen storage, 1.7 wt% in Ti25Zr25Nb15V15Ta20, were confirmed by gas-solid reactions. This HEA also has high corrosion resistance in acidic and saline environments ideal for coatings and surgical tools/implants.",
keywords = "Alkaline corrosion, EIS, gas-solid reactions, High entropy alloy, Passive film, STEM",
author = "Baran Sarac and Vladislav Zadorozhnyy and Ivanov, {Yurii P.} and Florian Spieckermann and Semen Klyamkin and Elena Berdonosova and Mikhail Serov and Sergey Kaloshkin and Greer, {A. Lindsay} and Sarac, {A. Sezai} and J{\"u}rgen Eckert",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",
year = "2021",
month = dec,
doi = "10.1016/j.corsci.2021.109880",
language = "English",
volume = "193.2021",
journal = "Corrosion science",
issn = "0010-938X",
publisher = "Elsevier",
number = "December",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Transition metal-based high entropy alloy microfiber electrodes

T2 - Corrosion behavior and hydrogen activity

AU - Sarac, Baran

AU - Zadorozhnyy, Vladislav

AU - Ivanov, Yurii P.

AU - Spieckermann, Florian

AU - Klyamkin, Semen

AU - Berdonosova, Elena

AU - Serov, Mikhail

AU - Kaloshkin, Sergey

AU - Greer, A. Lindsay

AU - Sarac, A. Sezai

AU - Eckert, Jürgen

N1 - Publisher Copyright: © 2021 Elsevier Ltd

PY - 2021/12

Y1 - 2021/12

N2 - This contribution reveals ultra-high corrosion resistance of high entropy alloys (HEAs), i.e. Ti20Zr20Nb15V15Hf15Ta15 of 1.85 µm yr–1 in alkaline environment, adverting their use for battery/fuel cell components. Formation of several nanometers passive oxide layer confirmed by scanning transmission electron microscopy accounts for corrosion resistance which increases with TiOx content. Cathodic Tafel slope of 67 mV dec–1 and large transfer coefficient of 0.82 obtained for Ti20Zr20Nb20V20Ta20 suggest its use for hydrogen electrocatalysis. High amounts of hydrogen storage, 1.7 wt% in Ti25Zr25Nb15V15Ta20, were confirmed by gas-solid reactions. This HEA also has high corrosion resistance in acidic and saline environments ideal for coatings and surgical tools/implants.

AB - This contribution reveals ultra-high corrosion resistance of high entropy alloys (HEAs), i.e. Ti20Zr20Nb15V15Hf15Ta15 of 1.85 µm yr–1 in alkaline environment, adverting their use for battery/fuel cell components. Formation of several nanometers passive oxide layer confirmed by scanning transmission electron microscopy accounts for corrosion resistance which increases with TiOx content. Cathodic Tafel slope of 67 mV dec–1 and large transfer coefficient of 0.82 obtained for Ti20Zr20Nb20V20Ta20 suggest its use for hydrogen electrocatalysis. High amounts of hydrogen storage, 1.7 wt% in Ti25Zr25Nb15V15Ta20, were confirmed by gas-solid reactions. This HEA also has high corrosion resistance in acidic and saline environments ideal for coatings and surgical tools/implants.

KW - Alkaline corrosion

KW - EIS

KW - gas-solid reactions

KW - High entropy alloy

KW - Passive film

KW - STEM

UR - http://www.scopus.com/inward/record.url?scp=85120702013&partnerID=8YFLogxK

U2 - 10.1016/j.corsci.2021.109880

DO - 10.1016/j.corsci.2021.109880

M3 - Article

AN - SCOPUS:85120702013

VL - 193.2021

JO - Corrosion science

JF - Corrosion science

SN - 0010-938X

IS - December

M1 - 109880

ER -

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