Stabilisierung von UHMW-PE mit alpha-Tocopherol unterhalb des Schmelzpunkts

Research output: ThesisDiploma Thesis

Authors

Abstract

In previous projects two methods for stabilizing crosslinked ultra high molecular weight polethylene (UHMW-PE) above the melting point have been presented. Method 1 operates at low pressure levels, while method 2 uses supercritical carbondioxide (CO2) at very high pressure levels for loading the polymer with vitamine E. In this work the suitability of both methods concerning a stabilization below the melting point at 138°C was investigated. For method 2 various impregnation temperatures, impregnation pressure levels, impregnation periods and alpha-tocopherol concentrations were used to achieve optimal stabilization conditions. Secondly, the depressurization process was optimized. A too fast decrease of pressure results in damaged samples due to expanding CO2. For method 1 various diffusion times were tested. Analyzation methods such as differential scanning calorimetry (DSC), fourier transformation infrared-spectroscopy (FTIR, transmissionelectron micoscopy (TEM), light microscopy and digital fotography were used for detection of crystallinity, alpha-tocopherol distribution and microstructural changes and damages respectively. Both methods are well suited to stabilize UHMW-PE below its melting point, with better results for method 2.

Details

Translated title of the contributionStabilization of UHMW-PE with alpha-tocopherol below the melting point
Original languageGerman
Supervisors/Advisors
Award date30 Jun 2006
Publication statusPublished - 2006