TY - JOUR

T1 - Self-healable epoxy/graphene oxide vitrimers and their recyclable glass fiber reinforced composites

AU - Sharma, Harsh

AU - Bijalwan, Viranchika

AU - Mourad, Abdel Hamid I.

AU - Kumar, Ajay

AU - Schlögl, Sandra

AU - Rana, Sravendra

N1 - Publisher Copyright: © The Author(s) 2024.

PY - 2024/10/24

Y1 - 2024/10/24

N2 - Glass fiber-reinforced polymers (GFRPs) made from thermoset polymers have been widely used across various industries. However, these composites have significant drawbacks, including poor interfacial adhesion between the fiber and matrix, as well as a substantial contribution to waste and environmental pollution due to the challenges in recycling, reprocessing, and reuse. Herein, firstly graphene oxide (GO) was incorporated in vitrimer matrix to fabricate recyclable vitrimer nanocomposites with improved interfacial interaction, high thermal stability, low dielectric constant, fast stress relaxation as well as rapid self-healing ability. The nanocomposite with 0.2 wt% GO is optimized to achieve excellent remoulding (89% of flexural strength) and self-healing (60 min for a 48 μm scratch) properties due to dynamic disulfide bond exchange mechanism. Furthermore, epoxy/GO matrix was used to develop glass fiber reinforced composites via vacuum assisted resin infusion molding process (VARIM). The developed composites demonstrate tremendous mechanical strength (250 MPa), shape-memory, weldability, and degradable properties. Due to the rapid chemical degradation of epoxy vitrimer under mild conditions in the thiol (2-mercaptoethanol and 1-otanethiol), facilitated by thiol disulfide exchange reaction, glass fibers (GFs) can be effectively recycled. The performance of recycled glass fibers closely matches that of original fibers, exhibiting nearly identical woven structure and mechanical properties. The single yarn of recycled glass fibers can achieve tensile strength of 85% (1-octanethiol) and 72% (2-mercaptoethanol) of the original glass fibers, thus, the recycling of glass fibers would be highly advantageous in terms of achieving the sustainability goals.

AB - Glass fiber-reinforced polymers (GFRPs) made from thermoset polymers have been widely used across various industries. However, these composites have significant drawbacks, including poor interfacial adhesion between the fiber and matrix, as well as a substantial contribution to waste and environmental pollution due to the challenges in recycling, reprocessing, and reuse. Herein, firstly graphene oxide (GO) was incorporated in vitrimer matrix to fabricate recyclable vitrimer nanocomposites with improved interfacial interaction, high thermal stability, low dielectric constant, fast stress relaxation as well as rapid self-healing ability. The nanocomposite with 0.2 wt% GO is optimized to achieve excellent remoulding (89% of flexural strength) and self-healing (60 min for a 48 μm scratch) properties due to dynamic disulfide bond exchange mechanism. Furthermore, epoxy/GO matrix was used to develop glass fiber reinforced composites via vacuum assisted resin infusion molding process (VARIM). The developed composites demonstrate tremendous mechanical strength (250 MPa), shape-memory, weldability, and degradable properties. Due to the rapid chemical degradation of epoxy vitrimer under mild conditions in the thiol (2-mercaptoethanol and 1-otanethiol), facilitated by thiol disulfide exchange reaction, glass fibers (GFs) can be effectively recycled. The performance of recycled glass fibers closely matches that of original fibers, exhibiting nearly identical woven structure and mechanical properties. The single yarn of recycled glass fibers can achieve tensile strength of 85% (1-octanethiol) and 72% (2-mercaptoethanol) of the original glass fibers, thus, the recycling of glass fibers would be highly advantageous in terms of achieving the sustainability goals.

KW - Glass fiber

KW - graphene oxide

KW - recycling

KW - self-healing

KW - vitrimers

UR - http://www.scopus.com/inward/record.url?scp=85208195172&partnerID=8YFLogxK

U2 - 10.1177/07316844241295848

DO - 10.1177/07316844241295848

M3 - Article

AN - SCOPUS:85208195172

JO - Journal of Reinforced Plastics and Composites

JF - Journal of Reinforced Plastics and Composites

SN - 0731-6844

IS - ??? Stand: 2. Jänner 2025

ER -