Reactive interdiffusion of an Al film and a CoCrFeNi high-entropy alloy

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Reactive interdiffusion of an Al film and a CoCrFeNi high-entropy alloy. / Zhang, Zaoli; Ketov, Sergey V.; Fellner, Simon et al.
In: Materials and Design, Vol. 216.2022, No. April, 110530, 10.03.2022.

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Zhang Z, Ketov SV, Fellner S, Sheng H, Mitterer C, Song KK et al. Reactive interdiffusion of an Al film and a CoCrFeNi high-entropy alloy. Materials and Design. 2022 Mar 10;216.2022(April):110530. doi: 10.1016/j.matdes.2022.110530

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Zhang, Zaoli ; Ketov, Sergey V. ; Fellner, Simon et al. / Reactive interdiffusion of an Al film and a CoCrFeNi high-entropy alloy. In: Materials and Design. 2022 ; Vol. 216.2022, No. April.

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@article{40bfceefd0c94aa098798dab619301f4,
title = "Reactive interdiffusion of an Al film and a CoCrFeNi high-entropy alloy",
abstract = "Diffusion plays a significant role in phase formation and transformation in solid-state alloys. In order to determine the influence of element diffusion on the phase formation and transition behavior in a high-entropy alloy (HEA), a systematic study on the reactive diffusion of Al and a CoCrFeNi HEA was carried out. It is demonstrated that thermodynamic and kinetic effects play a coupled role in the phase evolution in the HEA, among which the thermodynamic effect governs the evolution of major phases. The diffusion direction of the elements is controlled by the Gibbs free energy gradient in front of the interface, while the sluggish diffusion effect does not play a dominant role during reactive diffusion. At an annealing temperature of 773 K, the enthalpy of mixing dominates the total energy and therefore has a significant impact on the phase evolution during reactive diffusion.",
author = "Zaoli Zhang and Ketov, {Sergey V.} and Simon Fellner and Huaping Sheng and Christian Mitterer and K.K. Song and C. Gammer and J{\"u}rgen Eckert",
note = "Publisher Copyright: {\textcopyright} 2022 The Authors",
year = "2022",
month = mar,
day = "10",
doi = "10.1016/j.matdes.2022.110530",
language = "English",
volume = "216.2022",
journal = "Materials and Design",
issn = "0264-1275",
publisher = "Elsevier",
number = "April",

}

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TY - JOUR

T1 - Reactive interdiffusion of an Al film and a CoCrFeNi high-entropy alloy

AU - Zhang, Zaoli

AU - Ketov, Sergey V.

AU - Fellner, Simon

AU - Sheng, Huaping

AU - Mitterer, Christian

AU - Song, K.K.

AU - Gammer, C.

AU - Eckert, Jürgen

N1 - Publisher Copyright: © 2022 The Authors

PY - 2022/3/10

Y1 - 2022/3/10

N2 - Diffusion plays a significant role in phase formation and transformation in solid-state alloys. In order to determine the influence of element diffusion on the phase formation and transition behavior in a high-entropy alloy (HEA), a systematic study on the reactive diffusion of Al and a CoCrFeNi HEA was carried out. It is demonstrated that thermodynamic and kinetic effects play a coupled role in the phase evolution in the HEA, among which the thermodynamic effect governs the evolution of major phases. The diffusion direction of the elements is controlled by the Gibbs free energy gradient in front of the interface, while the sluggish diffusion effect does not play a dominant role during reactive diffusion. At an annealing temperature of 773 K, the enthalpy of mixing dominates the total energy and therefore has a significant impact on the phase evolution during reactive diffusion.

AB - Diffusion plays a significant role in phase formation and transformation in solid-state alloys. In order to determine the influence of element diffusion on the phase formation and transition behavior in a high-entropy alloy (HEA), a systematic study on the reactive diffusion of Al and a CoCrFeNi HEA was carried out. It is demonstrated that thermodynamic and kinetic effects play a coupled role in the phase evolution in the HEA, among which the thermodynamic effect governs the evolution of major phases. The diffusion direction of the elements is controlled by the Gibbs free energy gradient in front of the interface, while the sluggish diffusion effect does not play a dominant role during reactive diffusion. At an annealing temperature of 773 K, the enthalpy of mixing dominates the total energy and therefore has a significant impact on the phase evolution during reactive diffusion.

UR - http://www.scopus.com/inward/record.url?scp=85126599351&partnerID=8YFLogxK

U2 - 10.1016/j.matdes.2022.110530

DO - 10.1016/j.matdes.2022.110530

M3 - Article

VL - 216.2022

JO - Materials and Design

JF - Materials and Design

SN - 0264-1275

IS - April

M1 - 110530

ER -