Asymmetric supercapacitors based on biomass-derived porous activated carbon (PAC)/1D manganese oxide (MnO2) electrodes with high power and energy densities

Research output: Contribution to journalArticleResearchpeer-review

Authors

  • Young-Seok Lee
  • Aravindha Raja Selvaraj
  • Claus Rebholz
  • Rajmohan Rajendiran
  • Vivekanandan Raman
  • Heeje Kim
  • John Anthuvan Rajesh
  • Vijay Mohan Nagulapati
  • Tae Hwan Oh
  • Peter Jerome
  • Sung-Shin Kim

External Organisational units

  • Pusan National University
  • Sungkyunkwan University
  • Yeungnam University
  • Ulsan National Institute of Science and Technology
  • University of Cyprus
  • Gachon University

Abstract

In this study, we present the electrochemical performance of an asymmetric supercapacitor (ASC) composed of one-dimensional manganese oxide (MnO 2) nanorods embedded in porous activated carbon sheets (MnO 2/PAC) as the positive electrode (positrode), and renewable porous activated carbon (PAC) as the negative electrode (negatrode). This configuration facilitates a high rate of charge/discharge while maintaining substantial specific capacity. The MnO 2/PAC composite was successfully synthesized using a hydrothermal technique, while the PAC material was produced through pyrolysis reaction. The MnO 2/PAC composite exhibited a maximum specific capacitance of 208.75F g −1 at 0.5 A/g and demonstrated a cyclic stability of 87.43 % in neutral aqueous electrolytes. This notable electrochemical performance is attributed to the significant contribution of the high pseudo-capacitance offered by dense MnO 2 nanorods, in addition to the expansive surface area of the activated carbon sheets with closely packed structures. The ASC constructed as PAC//MnO 2/PAC displayed a high energy density of 23.3 Wh kg −1 and a power density of 350.4 W kg −1 at a current density of 0.5 A/g. Furthermore, the device showcased exceptional cycling stability, retaining 90.3 % at a current density of 4 A/g. These results underscore the substantial untapped potential of ASC devices for innovative applications in advanced energy storage.

Details

Original languageEnglish
Article number117368
Number of pages10
JournalMaterials science and engineering B (Solid-state materials for advanced technology)
Volume304.2024
Issue numberJune
Early online date14 Apr 2024
DOIs
Publication statusPublished - Jun 2024