TY - JOUR

T1 - Accelerated Thermo-Catalytic Degradation of Perfluoropolyether (PFPE) Lubricants for Space Applications

AU - Gleirscher, Milena

AU - Wolfberger, Archim

AU - Schlögl, Sandra

AU - Hołyńska, Małgorzata

AU - Hausberger, Andreas

N1 - Publisher Copyright: © 2023 by the authors.

PY - 2023/2/14

Y1 - 2023/2/14

N2 - Perfluoropolyethers (PFPE) are a class of frequently used lubricants in space applications due to their high stability under demanding conditions. However, they are susceptible to aging, with the aging mechanism being dependent on the specific material combination and storage condition. A Lewis-acid-induced thermo-catalytic degradation mechanism is of concern, for example, under steel-on-steel sliding contact, and can be relevant for long-term storage (LTS). Accelerated aging experiments were performed on Fomblin® Z25 and Krytox™ 143AC to investigate thermal stability under the influence of iron(III) fluoride (FeF3) at elevated temperatures (180 °C, 200 °C, and 220 °C) up to a total duration of 2000 h. The degradation effects were monitored via selected analysis techniques: mass loss of the samples due to degradation and subsequent evaporation during aging, FTIR spectroscopy to investigate changes to the chemical structure, dynamic viscosity measurements for the investigation of a potential impact due to changes in molecular mass, and a ball-on-disc tribological test setup to obtain friction behavior of the aged lubricants. Distinct differences between the two types of PFPE lubricants regarding stability to thermo-catalytic degradation were found. Fomblin® Z25 was highly affected by the presence of FeF3 within the selected aging conditions, exhibiting high mass loss, a significant drop in dynamic viscosity, and an increased coefficient of friction due to degradation reactions.

AB - Perfluoropolyethers (PFPE) are a class of frequently used lubricants in space applications due to their high stability under demanding conditions. However, they are susceptible to aging, with the aging mechanism being dependent on the specific material combination and storage condition. A Lewis-acid-induced thermo-catalytic degradation mechanism is of concern, for example, under steel-on-steel sliding contact, and can be relevant for long-term storage (LTS). Accelerated aging experiments were performed on Fomblin® Z25 and Krytox™ 143AC to investigate thermal stability under the influence of iron(III) fluoride (FeF3) at elevated temperatures (180 °C, 200 °C, and 220 °C) up to a total duration of 2000 h. The degradation effects were monitored via selected analysis techniques: mass loss of the samples due to degradation and subsequent evaporation during aging, FTIR spectroscopy to investigate changes to the chemical structure, dynamic viscosity measurements for the investigation of a potential impact due to changes in molecular mass, and a ball-on-disc tribological test setup to obtain friction behavior of the aged lubricants. Distinct differences between the two types of PFPE lubricants regarding stability to thermo-catalytic degradation were found. Fomblin® Z25 was highly affected by the presence of FeF3 within the selected aging conditions, exhibiting high mass loss, a significant drop in dynamic viscosity, and an increased coefficient of friction due to degradation reactions.

KW - accelerated aging

KW - liquid lubricants

KW - long-term storage

KW - perfluoropolyether

KW - PFPE

KW - thermo-catalytic degradation

UR - http://www.scopus.com/inward/record.url?scp=85149064236&partnerID=8YFLogxK

U2 - 10.3390/lubricants11020081

DO - 10.3390/lubricants11020081

M3 - Article

AN - SCOPUS:85149064236

VL - 11.2023

JO - Lubricants

JF - Lubricants

SN - 2075-4442

IS - 2

M1 - 81

ER -