Tuning mechanical properties of ultrafine-grained tungsten by manipulating grain boundary chemistry
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in: Acta materialia, Jahrgang 232.2022, Nr. 15 June, 117939, 19.04.2022.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
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TY - JOUR
T1 - Tuning mechanical properties of ultrafine-grained tungsten by manipulating grain boundary chemistry
AU - Wurmshuber, Michael
AU - Jakob, Severin
AU - Doppermann, Simon
AU - Wurster, Stefan
AU - Bodlos, Rishi
AU - Romaner, Lorenz
AU - Maier-Kiener, Verena
AU - Kiener, Daniel
N1 - Publisher Copyright: © 2022
PY - 2022/4/19
Y1 - 2022/4/19
N2 - Tungsten is, due to a combination of high strength and good physical properties, frequently considered for high-performance applications in the harshest environments. Oftentimes its inherent brittleness and low ductility stand in the way of a successful deployment in these fields. Since tungsten has been proposed as divertor material for nuclear fusion reactors, an improvement of ductility and fracture toughness is essential. An obvious first step to increase these properties is to reduce the grain size to the ultrafine-grained regime. As this still leaves the material with a relatively low-energy intercrystalline fracture mode, this work takes a step further. With the help of doping elements, which are identified from ab-initio simulations, an attempt to increase grain boundary cohesion of ultra-fine grained tungsten to improve ductility is made. After fabrication of the doped samples from powders using severe plastic deformation, thorough microstructural investigations and extensive mechanical characterization, utilizing various small-scale testing techniques, are combined to assess the properties of the materials. We report that the addition of boron and hafnium can significantly increase the bending strength and bending ductility of ultra-fine grained tungsten. An additional heat treatment of the boron doped sample amplifies this effect even further, drastically increasing the strength and overall mechanical properties due to a combination of hardening-by-annealing and increased grain boundary segregation. Thus, an effective way to adaptively improve the mechanical properties of tungsten by manipulating grain boundary chemistry is reported, validating grain boundary segregation engineering as a powerful tool for enhancing damage tolerance in brittle materials.
AB - Tungsten is, due to a combination of high strength and good physical properties, frequently considered for high-performance applications in the harshest environments. Oftentimes its inherent brittleness and low ductility stand in the way of a successful deployment in these fields. Since tungsten has been proposed as divertor material for nuclear fusion reactors, an improvement of ductility and fracture toughness is essential. An obvious first step to increase these properties is to reduce the grain size to the ultrafine-grained regime. As this still leaves the material with a relatively low-energy intercrystalline fracture mode, this work takes a step further. With the help of doping elements, which are identified from ab-initio simulations, an attempt to increase grain boundary cohesion of ultra-fine grained tungsten to improve ductility is made. After fabrication of the doped samples from powders using severe plastic deformation, thorough microstructural investigations and extensive mechanical characterization, utilizing various small-scale testing techniques, are combined to assess the properties of the materials. We report that the addition of boron and hafnium can significantly increase the bending strength and bending ductility of ultra-fine grained tungsten. An additional heat treatment of the boron doped sample amplifies this effect even further, drastically increasing the strength and overall mechanical properties due to a combination of hardening-by-annealing and increased grain boundary segregation. Thus, an effective way to adaptively improve the mechanical properties of tungsten by manipulating grain boundary chemistry is reported, validating grain boundary segregation engineering as a powerful tool for enhancing damage tolerance in brittle materials.
UR - https://pure.unileoben.ac.at/portal/en/publications/tuning-mechanical-properties-of-ultrafinegrained-tungsten-by-manipulating-grain-boundary-chemistry(6c26cde8-3c12-4228-a8e6-f3a78f21fa21).html
UR - http://www.scopus.com/inward/record.url?scp=85129471007&partnerID=8YFLogxK
U2 - 10.1016/j.actamat.2022.117939
DO - 10.1016/j.actamat.2022.117939
M3 - Article
VL - 232.2022
JO - Acta materialia
JF - Acta materialia
SN - 1359-6454
IS - 15 June
M1 - 117939
ER -