Impact of Si on the high-temperature oxidation of AlCr(Si)N coatings
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in: JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, Jahrgang 100.2022, Nr. 20 February, 20.02.2022, S. 91-100.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
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TY - JOUR
T1 - Impact of Si on the high-temperature oxidation of AlCr(Si)N coatings
AU - Jäger, Nikolaus
AU - Meindlhumer, Michael
AU - Zitek, Michal
AU - Spor, Stefan
AU - Hruby, Hynek
AU - Nahif, Farwah
AU - Julin, Jaakoo
AU - Rosenthal, Martin
AU - Keckes, Jozef
AU - Mitterer, Christian
AU - Daniel, Rostislav
N1 - Publisher Copyright: © 2021
PY - 2022/2/20
Y1 - 2022/2/20
N2 - The resistance of wear protective coatings against oxidation is crucial for their use at high temperatures. Here, three nanocomposite AlCr(Si)N coatings with a fixed Al/Cr atomic ratio of 70/30 and a varying Si-content of 0 at.%, 2.5 at.% and 5 at.% were analyzed by differential scanning calorimetry, thermogravimetric analysis and X-ray in order to understand the oxidation behavior depending on their Si-content. Additionally, a partially oxidized AlCrSiN coating with 5 at.% Si on a sapphire substrate was studied across the coating thickness by depth-resolved cross-sectional X-ray nanodiffraction and scanning trans-mission electron microscopy to investigate the elemental composition, morphology, phases and residual stress evolution of the oxide scale and the non-oxidized coating underneath. The results reveal enhanced oxidation properties of the AlCr(Si)N coatings with increasing Si-content, as demonstrated by a retarded onset of oxidation to higher temperatures from 1100°C for AlCrN to 1260°C for the Si-containing coatings and a simultaneous deceleration of the oxidation process. After annealing of the AlCrSiN sample with 5 at.% Si at an extraordinary high temperature of 1400°C for 60 min in ambient air, three zones developed throughout the coating strongly differing in their composition and structure: (i) a dense oxide layer comprising an Al-rich and a Cr-rich zone formed at the very top, followed by (ii) a fine-grained transition zone with incomplete oxidation and (iii) a non-oxidized zone with a porous structure. The varying elemental composition of these zones is furthermore accompanied by micro-structural variations and a complex residual stress development revealed by cross-sectional X-ray nanodiffraction. The results provide a deeper understanding of the oxidation behavior of AlCr(Si)N coatings depending on their Si-content and the associated elemental, microstructural and residual stress evolution during high-temperature oxidation.
AB - The resistance of wear protective coatings against oxidation is crucial for their use at high temperatures. Here, three nanocomposite AlCr(Si)N coatings with a fixed Al/Cr atomic ratio of 70/30 and a varying Si-content of 0 at.%, 2.5 at.% and 5 at.% were analyzed by differential scanning calorimetry, thermogravimetric analysis and X-ray in order to understand the oxidation behavior depending on their Si-content. Additionally, a partially oxidized AlCrSiN coating with 5 at.% Si on a sapphire substrate was studied across the coating thickness by depth-resolved cross-sectional X-ray nanodiffraction and scanning trans-mission electron microscopy to investigate the elemental composition, morphology, phases and residual stress evolution of the oxide scale and the non-oxidized coating underneath. The results reveal enhanced oxidation properties of the AlCr(Si)N coatings with increasing Si-content, as demonstrated by a retarded onset of oxidation to higher temperatures from 1100°C for AlCrN to 1260°C for the Si-containing coatings and a simultaneous deceleration of the oxidation process. After annealing of the AlCrSiN sample with 5 at.% Si at an extraordinary high temperature of 1400°C for 60 min in ambient air, three zones developed throughout the coating strongly differing in their composition and structure: (i) a dense oxide layer comprising an Al-rich and a Cr-rich zone formed at the very top, followed by (ii) a fine-grained transition zone with incomplete oxidation and (iii) a non-oxidized zone with a porous structure. The varying elemental composition of these zones is furthermore accompanied by micro-structural variations and a complex residual stress development revealed by cross-sectional X-ray nanodiffraction. The results provide a deeper understanding of the oxidation behavior of AlCr(Si)N coatings depending on their Si-content and the associated elemental, microstructural and residual stress evolution during high-temperature oxidation.
UR - http://www.scopus.com/inward/record.url?scp=85114666296&partnerID=8YFLogxK
U2 - 10.1016/j.jmst.2021.04.065
DO - 10.1016/j.jmst.2021.04.065
M3 - Article
VL - 100.2022
SP - 91
EP - 100
JO - JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
JF - JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
SN - 1005-0302
IS - 20 February
ER -