Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
Standard
in: Polymers, Jahrgang 11.2019, Nr. 7, 17.07.2019, S. 1192-1202.
Publikationen: Beitrag in Fachzeitschrift › Artikel › Forschung › (peer-reviewed)
Harvard
APA
Vancouver
Author
Bibtex - Download
}
RIS (suitable for import to EndNote) - Download
TY - JOUR
T1 - Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology
AU - Galakhova, Anastasiia
AU - Santiago-Calvo, Mercedes
AU - Tirado-Mediavilla, Josias
AU - Villafane, Fernando
AU - Rodriguez-Perez, Miguel Angel
AU - Rieß, Gisbert
N1 - Publisher Copyright: © 2019 by the authors.
PY - 2019/7/17
Y1 - 2019/7/17
N2 - This paper presents a new methodology based on gas chromatography-mass spectrometry (GCMS) in order to separate and quantify the gases presented inside the cells of rigid polyurethane (RPU) foams. To demonstrate this novel methodology, the gas composition along more than three years of aging is herein determined for two samples: a reference foam and foam with 1.5 wt% of talc. The GCMS method was applied, on one hand, for the accurate determination of C 5H 10 and CO 2 cell gases used as blowing agents and, on the other hand, for N 2 and O 2 air gases that diffuse rapidly from the surrounding environment into foam cells. GCMS results showed that CO2 leaves foam after 2.5 month (from 21% to 0.03% for reference foam and from 17% to 0.03% for foam with 1.5% talc). C 5H 10 deviates during 3.5 months (from 28% up to 39% for reference foam and from 29% up to 36% for foam with talc), then it starts to leave the foam and after 3.5 year its content is 13% for reference and 10% for foam with talc. Air diffuses inside the cells faster for one year (from 51% up to 79% for reference and from 54% up to 81% for foam with talc) and then more slowly for 3.5 years (reaching 86% for reference and 90% for foam with talc). Thus, the fast and simple presented methodology provides valuable information to understand the long-term thermal conductivity of the RPU foams.
AB - This paper presents a new methodology based on gas chromatography-mass spectrometry (GCMS) in order to separate and quantify the gases presented inside the cells of rigid polyurethane (RPU) foams. To demonstrate this novel methodology, the gas composition along more than three years of aging is herein determined for two samples: a reference foam and foam with 1.5 wt% of talc. The GCMS method was applied, on one hand, for the accurate determination of C 5H 10 and CO 2 cell gases used as blowing agents and, on the other hand, for N 2 and O 2 air gases that diffuse rapidly from the surrounding environment into foam cells. GCMS results showed that CO2 leaves foam after 2.5 month (from 21% to 0.03% for reference foam and from 17% to 0.03% for foam with 1.5% talc). C 5H 10 deviates during 3.5 months (from 28% up to 39% for reference foam and from 29% up to 36% for foam with talc), then it starts to leave the foam and after 3.5 year its content is 13% for reference and 10% for foam with talc. Air diffuses inside the cells faster for one year (from 51% up to 79% for reference and from 54% up to 81% for foam with talc) and then more slowly for 3.5 years (reaching 86% for reference and 90% for foam with talc). Thus, the fast and simple presented methodology provides valuable information to understand the long-term thermal conductivity of the RPU foams.
UR - http://www.scopus.com/inward/record.url?scp=85070418011&partnerID=8YFLogxK
U2 - 10.3390/polym11071192
DO - 10.3390/polym11071192
M3 - Article
VL - 11.2019
SP - 1192
EP - 1202
JO - Polymers
JF - Polymers
SN - 2073-4360
IS - 7
ER -