Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology

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Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology. / Galakhova, Anastasiia; Santiago-Calvo, Mercedes; Tirado-Mediavilla, Josias et al.
in: Polymers, Jahrgang 11.2019, Nr. 7, 17.07.2019, S. 1192-1202.

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

Harvard

Galakhova, A, Santiago-Calvo, M, Tirado-Mediavilla, J, Villafane, F, Rodriguez-Perez, MA & Rieß, G 2019, 'Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology', Polymers, Jg. 11.2019, Nr. 7, S. 1192-1202. https://doi.org/10.3390/polym11071192

APA

Vancouver

Galakhova A, Santiago-Calvo M, Tirado-Mediavilla J, Villafane F, Rodriguez-Perez MA, Rieß G. Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology. Polymers. 2019 Jul 17;11.2019(7):1192-1202. doi: 10.3390/polym11071192

Author

Galakhova, Anastasiia ; Santiago-Calvo, Mercedes ; Tirado-Mediavilla, Josias et al. / Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology. in: Polymers. 2019 ; Jahrgang 11.2019, Nr. 7. S. 1192-1202.

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@article{202fdc72955c4a378ab8e79877eea9ec,
title = "Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology",
abstract = "This paper presents a new methodology based on gas chromatography-mass spectrometry (GCMS) in order to separate and quantify the gases presented inside the cells of rigid polyurethane (RPU) foams. To demonstrate this novel methodology, the gas composition along more than three years of aging is herein determined for two samples: a reference foam and foam with 1.5 wt% of talc. The GCMS method was applied, on one hand, for the accurate determination of C 5H 10 and CO 2 cell gases used as blowing agents and, on the other hand, for N 2 and O 2 air gases that diffuse rapidly from the surrounding environment into foam cells. GCMS results showed that CO2 leaves foam after 2.5 month (from 21% to 0.03% for reference foam and from 17% to 0.03% for foam with 1.5% talc). C 5H 10 deviates during 3.5 months (from 28% up to 39% for reference foam and from 29% up to 36% for foam with talc), then it starts to leave the foam and after 3.5 year its content is 13% for reference and 10% for foam with talc. Air diffuses inside the cells faster for one year (from 51% up to 79% for reference and from 54% up to 81% for foam with talc) and then more slowly for 3.5 years (reaching 86% for reference and 90% for foam with talc). Thus, the fast and simple presented methodology provides valuable information to understand the long-term thermal conductivity of the RPU foams. ",
author = "Anastasiia Galakhova and Mercedes Santiago-Calvo and Josias Tirado-Mediavilla and Fernando Villafane and Rodriguez-Perez, {Miguel Angel} and Gisbert Rie{\ss}",
note = "Publisher Copyright: {\textcopyright} 2019 by the authors.",
year = "2019",
month = jul,
day = "17",
doi = "10.3390/polym11071192",
language = "English",
volume = "11.2019",
pages = "1192--1202",
journal = "Polymers",
issn = "2073-4360",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "7",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Identification and Quantification of Cell Gas Evolution in Rigid Polyurethane Foams by Novel GCMS Methodology

AU - Galakhova, Anastasiia

AU - Santiago-Calvo, Mercedes

AU - Tirado-Mediavilla, Josias

AU - Villafane, Fernando

AU - Rodriguez-Perez, Miguel Angel

AU - Rieß, Gisbert

N1 - Publisher Copyright: © 2019 by the authors.

PY - 2019/7/17

Y1 - 2019/7/17

N2 - This paper presents a new methodology based on gas chromatography-mass spectrometry (GCMS) in order to separate and quantify the gases presented inside the cells of rigid polyurethane (RPU) foams. To demonstrate this novel methodology, the gas composition along more than three years of aging is herein determined for two samples: a reference foam and foam with 1.5 wt% of talc. The GCMS method was applied, on one hand, for the accurate determination of C 5H 10 and CO 2 cell gases used as blowing agents and, on the other hand, for N 2 and O 2 air gases that diffuse rapidly from the surrounding environment into foam cells. GCMS results showed that CO2 leaves foam after 2.5 month (from 21% to 0.03% for reference foam and from 17% to 0.03% for foam with 1.5% talc). C 5H 10 deviates during 3.5 months (from 28% up to 39% for reference foam and from 29% up to 36% for foam with talc), then it starts to leave the foam and after 3.5 year its content is 13% for reference and 10% for foam with talc. Air diffuses inside the cells faster for one year (from 51% up to 79% for reference and from 54% up to 81% for foam with talc) and then more slowly for 3.5 years (reaching 86% for reference and 90% for foam with talc). Thus, the fast and simple presented methodology provides valuable information to understand the long-term thermal conductivity of the RPU foams.

AB - This paper presents a new methodology based on gas chromatography-mass spectrometry (GCMS) in order to separate and quantify the gases presented inside the cells of rigid polyurethane (RPU) foams. To demonstrate this novel methodology, the gas composition along more than three years of aging is herein determined for two samples: a reference foam and foam with 1.5 wt% of talc. The GCMS method was applied, on one hand, for the accurate determination of C 5H 10 and CO 2 cell gases used as blowing agents and, on the other hand, for N 2 and O 2 air gases that diffuse rapidly from the surrounding environment into foam cells. GCMS results showed that CO2 leaves foam after 2.5 month (from 21% to 0.03% for reference foam and from 17% to 0.03% for foam with 1.5% talc). C 5H 10 deviates during 3.5 months (from 28% up to 39% for reference foam and from 29% up to 36% for foam with talc), then it starts to leave the foam and after 3.5 year its content is 13% for reference and 10% for foam with talc. Air diffuses inside the cells faster for one year (from 51% up to 79% for reference and from 54% up to 81% for foam with talc) and then more slowly for 3.5 years (reaching 86% for reference and 90% for foam with talc). Thus, the fast and simple presented methodology provides valuable information to understand the long-term thermal conductivity of the RPU foams.

UR - http://www.scopus.com/inward/record.url?scp=85070418011&partnerID=8YFLogxK

U2 - 10.3390/polym11071192

DO - 10.3390/polym11071192

M3 - Article

VL - 11.2019

SP - 1192

EP - 1202

JO - Polymers

JF - Polymers

SN - 2073-4360

IS - 7

ER -