Effect of Microstructure on the Degradation of La0.6Sr0.4CoO3– δ Electrodes in Dry and Humid Atmospheres

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Effect of Microstructure on the Degradation of La0.6Sr0.4CoO3– δ Electrodes in Dry and Humid Atmospheres. / Egger, Andreas; Perz, Martin; Bucher, Edith et al.
in: Fuel Cells, Jahrgang 19.2019, Nr. 4, 20.08.2019, S. 458-471.

Publikationen: Beitrag in FachzeitschriftArtikelForschung(peer-reviewed)

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@article{6fc6989ac6e8458fa6b4a4cbb355af7a,
title = "Effect of Microstructure on the Degradation of La0.6Sr0.4CoO3– δ Electrodes in Dry and Humid Atmospheres",
abstract = "La0.6Sr0.4CoO3-δ electrode layers with three different microstructures were manufactured by screen-printing, spin-coating and infiltration into a porous Ce0.9Gd0.1O1.95 backbone. Electrode performance was monitored at 700°C in 20% O2 over periods of 1600 to 3860 hours by means of electrochemical impedance spectroscopy under open circuit conditions. Reference measurements were performed in dry atmospheres, where significant electrode activation was observed for cells with spin-coated and infiltrated electrodes. Subsequently, the relative humidity level in the surrounding atmosphere was set to 30% and further raised to 60%, thus simulating SOFC operation with ambient air without pre-drying. While no performance loss could be observed in dry atmospheres, significant degradation occurred in humid atmospheres with pronounced differences between degradation rates of half cells with different electrode microstructures. Post-test analyses by SEM and STEM were employed to identify the causes for the observed differences in degradation behavior. For screen-printed cells, the surface of the degraded electrodes was covered with small crystallites, probably consisting of SrO formed by Sr-segregation and surface precipitation, where humidity was found to be a crucial factor. For spin-coated and infiltrated electrodes, poisoning by impurities (Si, Cr, S) and particle coarsening were identified as potential causes.",
author = "Andreas Egger and Martin Perz and Edith Bucher and Christian Gspan and Werner Sitte",
year = "2019",
month = aug,
day = "20",
doi = "10.1002/fuce.201900006",
language = "English",
volume = "19.2019",
pages = "458--471",
journal = "Fuel Cells",
issn = "1615-6846",
publisher = "John Wiley & Sons, Gro{\ss}britannien",
number = "4",

}

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TY - JOUR

T1 - Effect of Microstructure on the Degradation of La0.6Sr0.4CoO3– δ Electrodes in Dry and Humid Atmospheres

AU - Egger, Andreas

AU - Perz, Martin

AU - Bucher, Edith

AU - Gspan, Christian

AU - Sitte, Werner

PY - 2019/8/20

Y1 - 2019/8/20

N2 - La0.6Sr0.4CoO3-δ electrode layers with three different microstructures were manufactured by screen-printing, spin-coating and infiltration into a porous Ce0.9Gd0.1O1.95 backbone. Electrode performance was monitored at 700°C in 20% O2 over periods of 1600 to 3860 hours by means of electrochemical impedance spectroscopy under open circuit conditions. Reference measurements were performed in dry atmospheres, where significant electrode activation was observed for cells with spin-coated and infiltrated electrodes. Subsequently, the relative humidity level in the surrounding atmosphere was set to 30% and further raised to 60%, thus simulating SOFC operation with ambient air without pre-drying. While no performance loss could be observed in dry atmospheres, significant degradation occurred in humid atmospheres with pronounced differences between degradation rates of half cells with different electrode microstructures. Post-test analyses by SEM and STEM were employed to identify the causes for the observed differences in degradation behavior. For screen-printed cells, the surface of the degraded electrodes was covered with small crystallites, probably consisting of SrO formed by Sr-segregation and surface precipitation, where humidity was found to be a crucial factor. For spin-coated and infiltrated electrodes, poisoning by impurities (Si, Cr, S) and particle coarsening were identified as potential causes.

AB - La0.6Sr0.4CoO3-δ electrode layers with three different microstructures were manufactured by screen-printing, spin-coating and infiltration into a porous Ce0.9Gd0.1O1.95 backbone. Electrode performance was monitored at 700°C in 20% O2 over periods of 1600 to 3860 hours by means of electrochemical impedance spectroscopy under open circuit conditions. Reference measurements were performed in dry atmospheres, where significant electrode activation was observed for cells with spin-coated and infiltrated electrodes. Subsequently, the relative humidity level in the surrounding atmosphere was set to 30% and further raised to 60%, thus simulating SOFC operation with ambient air without pre-drying. While no performance loss could be observed in dry atmospheres, significant degradation occurred in humid atmospheres with pronounced differences between degradation rates of half cells with different electrode microstructures. Post-test analyses by SEM and STEM were employed to identify the causes for the observed differences in degradation behavior. For screen-printed cells, the surface of the degraded electrodes was covered with small crystallites, probably consisting of SrO formed by Sr-segregation and surface precipitation, where humidity was found to be a crucial factor. For spin-coated and infiltrated electrodes, poisoning by impurities (Si, Cr, S) and particle coarsening were identified as potential causes.

UR - http://www.scopus.com/inward/record.url?scp=85068521116&partnerID=8YFLogxK

U2 - 10.1002/fuce.201900006

DO - 10.1002/fuce.201900006

M3 - Article

VL - 19.2019

SP - 458

EP - 471

JO - Fuel Cells

JF - Fuel Cells

SN - 1615-6846

IS - 4

ER -