TY - JOUR

T1 - Atomic insights on intermixing of nanoscale nitride multilayer triggered by nanoindentation

AU - Chen, Zhuo

AU - Zheng, Yong Hui

AU - Löfler, Lukas

AU - Bartosik, Matthias

AU - Nayak, Ganesh Kumar

AU - Renk, Oliver

AU - Holec, David

AU - Mayrhofer, Paul Heinz

AU - Zhang, Zaoli

N1 - Publisher Copyright: © 2021 The Author(s)

PY - 2021/8/1

Y1 - 2021/8/1

N2 - Mechanical properties of nanoscale multilayer coatings are to a large extent governed by the number of interfaces and their characteristics. While for a reduced layer thickness, increasing strength and toughness values have been reported, properties degrade for layer thicknesses of just several nanometers. Here, we report on an entirely overlooked phenomenon occurring during the indentation of nanolayers, presumably explaining the degradation of properties. Nanoindentation, commonly used to determine properties of hard coatings, is found to disrupt and intermix the multilayer structure due to the deformation imposed. Detailed electron microscopy studies and atomistic simulations provide evidence for intermixing in an epitaxial transition metal nitride superlattice thin film induced by nanoindentation. The formation of a solid solution reduces the interfacial density and leads to a sharp drop in the dislocation density. Our results confirm that plastic deformation causes the microstructure instability of nitride multilayer, which may further improve our understanding of multilayer strength mechanisms.

AB - Mechanical properties of nanoscale multilayer coatings are to a large extent governed by the number of interfaces and their characteristics. While for a reduced layer thickness, increasing strength and toughness values have been reported, properties degrade for layer thicknesses of just several nanometers. Here, we report on an entirely overlooked phenomenon occurring during the indentation of nanolayers, presumably explaining the degradation of properties. Nanoindentation, commonly used to determine properties of hard coatings, is found to disrupt and intermix the multilayer structure due to the deformation imposed. Detailed electron microscopy studies and atomistic simulations provide evidence for intermixing in an epitaxial transition metal nitride superlattice thin film induced by nanoindentation. The formation of a solid solution reduces the interfacial density and leads to a sharp drop in the dislocation density. Our results confirm that plastic deformation causes the microstructure instability of nitride multilayer, which may further improve our understanding of multilayer strength mechanisms.

UR - http://www.scopus.com/inward/record.url?scp=85107296826&partnerID=8YFLogxK

U2 - 10.1016/j.actamat.2021.117004

DO - 10.1016/j.actamat.2021.117004

M3 - Article

VL - 214

JO - Acta materialia

JF - Acta materialia

SN - 1359-6454

IS - 1 August

M1 - 117004

ER -